Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Carbon disulfide, a poisonous, flammable liquid, is an excellent solvent for phosphorus, sulfur, and some other nonmetals. A kinetic study of its gaseous decomposition reveals these data:
(a) Choose the rate law for the decomposition of CS2.
Rate = |
|
(b) Calculate the average value of the rate constant. Enter your answer in scientific notation.
![**Table of Experimental Data:**
This table represents a series of experiments analyzing the relationship between the initial concentration of carbon disulfide \([CS_2]\) and the initial reaction rate.
| **Experiment** | **Initial \([CS_2]\) (mol/L)** | **Initial Rate (mol/L·s)** |
|----------------|-------------------------------|---------------------------|
| 1 | 0.100 | \(2.7 \times 10^{-7}\) |
| 2 | 0.080 | \(2.2 \times 10^{-7}\) |
| 3 | 0.055 | \(1.5 \times 10^{-7}\) |
| 4 | 0.044 | \(1.2 \times 10^{-7}\) |
**Explanation:**
- The table compares four experiments where the initial concentration of \(CS_2\) was varied.
- The corresponding initial reaction rates are provided for each concentration.
- The concentration is measured in moles per liter (mol/L), and the reaction rates are given in moles per liter per second (mol/L·s).
- Observing the data, there is a trend that a decrease in the initial concentration of \(CS_2\) leads to a decrease in the initial reaction rate, suggesting a direct correlation between these variables.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F27f2016c-a020-4970-862b-78f0bce3c5de%2F7c4f076d-94f2-4485-a55b-45697d45fedd%2Fizq9ssi_processed.png&w=3840&q=75)
Transcribed Image Text:**Table of Experimental Data:**
This table represents a series of experiments analyzing the relationship between the initial concentration of carbon disulfide \([CS_2]\) and the initial reaction rate.
| **Experiment** | **Initial \([CS_2]\) (mol/L)** | **Initial Rate (mol/L·s)** |
|----------------|-------------------------------|---------------------------|
| 1 | 0.100 | \(2.7 \times 10^{-7}\) |
| 2 | 0.080 | \(2.2 \times 10^{-7}\) |
| 3 | 0.055 | \(1.5 \times 10^{-7}\) |
| 4 | 0.044 | \(1.2 \times 10^{-7}\) |
**Explanation:**
- The table compares four experiments where the initial concentration of \(CS_2\) was varied.
- The corresponding initial reaction rates are provided for each concentration.
- The concentration is measured in moles per liter (mol/L), and the reaction rates are given in moles per liter per second (mol/L·s).
- Observing the data, there is a trend that a decrease in the initial concentration of \(CS_2\) leads to a decrease in the initial reaction rate, suggesting a direct correlation between these variables.
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