EXERCISE 3.2 Predict the structures of the following ions. Include a description of distortions from the ideal angles (for example, less than 109.5° because...). NH, NH, 1, PCL-
EXERCISE 3.2 Predict the structures of the following ions. Include a description of distortions from the ideal angles (for example, less than 109.5° because...). NH, NH, 1, PCL-
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![EXAMPLE 3.4
SbF,- has a single lone pair on Sb. Its structure is therefore similar to SF,, with a lone
pair occupying an equatorial position. This lone pair causes considerable distortion,
giving an F-Sb-F (axial positions) angle of 155° and an F– Sb-F (equatorial)
angle of 90°.
SF;- has a single lone pair. Its structure is based on an octahedron, with the ion
distorted away from the lone pair, as in IF .
SeF,* has a single lone pair. This lone pair reduces the Se-F bond angle
significantly, to 94º.
EXERCISE 3.2 Predict the structures of the following ions. Include a description of
distortions from the ideal angles (for example, less than 109.5° because...).
NH, NH, I; PCl-](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fde636865-979d-4953-9827-8e5c6fdd8f2b%2F9a551c41-e38b-471a-ab1c-5908a2d95b09%2Fl8ootn9_processed.png&w=3840&q=75)
Transcribed Image Text:EXAMPLE 3.4
SbF,- has a single lone pair on Sb. Its structure is therefore similar to SF,, with a lone
pair occupying an equatorial position. This lone pair causes considerable distortion,
giving an F-Sb-F (axial positions) angle of 155° and an F– Sb-F (equatorial)
angle of 90°.
SF;- has a single lone pair. Its structure is based on an octahedron, with the ion
distorted away from the lone pair, as in IF .
SeF,* has a single lone pair. This lone pair reduces the Se-F bond angle
significantly, to 94º.
EXERCISE 3.2 Predict the structures of the following ions. Include a description of
distortions from the ideal angles (for example, less than 109.5° because...).
NH, NH, I; PCl-
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