Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![Example #3) 15mL of 2.0M HCI is mixed with 30mL of 0.75M KOH
HCI + KOH → H₂O + KCI
AHreaction =
Substance
H₂O
HC1
KC1
KOH
AHreaction=AHproducts-
AHreactants
AHreaction = (AHH20+ AHKCI) - (AHHCI + AHKOH)
AHreaction = (-286
+ -419
- 1kg1
Let's calculate the limiting reagent to determine how many mols of water will be formed:
Remember: Volume of reactant ÷ 1000 x Molarity of reactant x mole-to-mole ratio to water
Here's the first reactant: 15mL of 2.0M HCI
IS
1500
* 2.0
0.03 mol HCl
30
1000
Lof LOM KOH
Let's do this for the second reactant, 30mL of 0.75M KOH
0.75
0.0225 mol KOH
=
-)-(-164
-61
mol H₂O) x
AHf in kJ/mol
-286
-164
-419
-480
The limiting reagent is the compound that produced the fewest number of moles. Multiply that
number of moles buy the AH reaction that was calculated above
kJ/mol = -/-3725 kJ
-
+_ - 480
10.0225
Calcu
From here on out, you are on your own! Calculate the enthalpy of reaction, and then the
limiting reagent. Next multiply the enthalpy of reaction by the limiting reagent. Good luck!](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F50ee8c08-bdb6-49cd-9014-91cd3b523354%2Ff576e51b-d3de-488d-80ff-6cb3bc95af4a%2F56ouhx5_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Example #3) 15mL of 2.0M HCI is mixed with 30mL of 0.75M KOH
HCI + KOH → H₂O + KCI
AHreaction =
Substance
H₂O
HC1
KC1
KOH
AHreaction=AHproducts-
AHreactants
AHreaction = (AHH20+ AHKCI) - (AHHCI + AHKOH)
AHreaction = (-286
+ -419
- 1kg1
Let's calculate the limiting reagent to determine how many mols of water will be formed:
Remember: Volume of reactant ÷ 1000 x Molarity of reactant x mole-to-mole ratio to water
Here's the first reactant: 15mL of 2.0M HCI
IS
1500
* 2.0
0.03 mol HCl
30
1000
Lof LOM KOH
Let's do this for the second reactant, 30mL of 0.75M KOH
0.75
0.0225 mol KOH
=
-)-(-164
-61
mol H₂O) x
AHf in kJ/mol
-286
-164
-419
-480
The limiting reagent is the compound that produced the fewest number of moles. Multiply that
number of moles buy the AH reaction that was calculated above
kJ/mol = -/-3725 kJ
-
+_ - 480
10.0225
Calcu
From here on out, you are on your own! Calculate the enthalpy of reaction, and then the
limiting reagent. Next multiply the enthalpy of reaction by the limiting reagent. Good luck!
![Example #4) 50mL of 1.5M HCI is mixed with 60mL of 1.0M KOH
HCI + KOH → H₂O + KCI
AHf in kJ/mol
-286
-164
-419
-480
Note: this is the same reaction as example #3, so the AH reaction should be the same
Substance
H₂O
HCI
KCI
KOH
AHreaction=AHproducts- AHreactants
AHreaction =
-biki
Let's calculate the limiting reagent to determine how many mols of water will be formed:
Here's the first reactant: 50mL of 1.5M HCI
50 * 1.5.
1000
1.5 = 0.075 mol Hel
Let's do this for the second reactant, 60mL of 1.0M KOH
60
1000
* 1 = 0.obmolkott
Calculate the amount of energy released:
Call 0.06 * -61 = -3.66 kg](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F50ee8c08-bdb6-49cd-9014-91cd3b523354%2Ff576e51b-d3de-488d-80ff-6cb3bc95af4a%2Fwat5x99_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Example #4) 50mL of 1.5M HCI is mixed with 60mL of 1.0M KOH
HCI + KOH → H₂O + KCI
AHf in kJ/mol
-286
-164
-419
-480
Note: this is the same reaction as example #3, so the AH reaction should be the same
Substance
H₂O
HCI
KCI
KOH
AHreaction=AHproducts- AHreactants
AHreaction =
-biki
Let's calculate the limiting reagent to determine how many mols of water will be formed:
Here's the first reactant: 50mL of 1.5M HCI
50 * 1.5.
1000
1.5 = 0.075 mol Hel
Let's do this for the second reactant, 60mL of 1.0M KOH
60
1000
* 1 = 0.obmolkott
Calculate the amount of energy released:
Call 0.06 * -61 = -3.66 kg
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