Example 2.6-2 Dimensional Homogeneity and Dimensionless Groups (a) The Nernst equation is used to predict the voltage in a fuel cell as a function of the partial pressure of the gases. This formula can be rearranged to give: P,P2 H2 02 [2F(E-E,) Pu20 P2 RT If F has units of C/mol e', E and Eo have units of V, R has units of J/mol H,-K, and T has units of K, then what are the units on the constant 2? Strategy We can compare the prescribed units to determine the unknown units. Solution The term in the natural log must be dimensionless. Thus, noting that 1 V = 1 J/C, we can solve for the units on 2 as: J -K mol H, - K C J mole C RT mol F(E-E,) mol (b) A dimensionless group in heat transfer is the Prandtl number, given by: µC, Pr k

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Answer those blanks. Show complete solutions. (Chemical Engineering Calculations)
Example 2.6-2 Dimensional Homogeneity and Dimensionless Groups
(a) The Nernst equation is used to predict the voltage in a fuel cell as a function of the
partial pressure of the gases. This formula can be rearranged to give:
2F(E - E,)
= In
PH20 P12
RT
If F has units of C/mol e', E and Eŋ have units of V, R has units of J/mol H2-K, and T has
units of K, then what are the units on the constant 2?
Strategy
We can compare the prescribed units to determine the unknown units.
Solution
The term in the natural log must be dimensionless. Thus, noting that 1 V = 1 J/C, we can
solve for the units on 2 as:
J
K
mol H, – K
RT
mol
F(E – E,)
J
mol
mole C
(b) A dimensionless group in heat transfer is the Prandtl number, given by:
Pr =
k
If C, has units of J/g-K and k has units of W/m-K, then what are the units on the viscosity
Strategy
We can compare the prescribed units to determine the unknown units.
Solution
Noting that 1 W = 1 J/s, we can solve for the units on µ as:
k
W g-K J/s
m -K
J W
Transcribed Image Text:Example 2.6-2 Dimensional Homogeneity and Dimensionless Groups (a) The Nernst equation is used to predict the voltage in a fuel cell as a function of the partial pressure of the gases. This formula can be rearranged to give: 2F(E - E,) = In PH20 P12 RT If F has units of C/mol e', E and Eŋ have units of V, R has units of J/mol H2-K, and T has units of K, then what are the units on the constant 2? Strategy We can compare the prescribed units to determine the unknown units. Solution The term in the natural log must be dimensionless. Thus, noting that 1 V = 1 J/C, we can solve for the units on 2 as: J K mol H, – K RT mol F(E – E,) J mol mole C (b) A dimensionless group in heat transfer is the Prandtl number, given by: Pr = k If C, has units of J/g-K and k has units of W/m-K, then what are the units on the viscosity Strategy We can compare the prescribed units to determine the unknown units. Solution Noting that 1 W = 1 J/s, we can solve for the units on µ as: k W g-K J/s m -K J W
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