Example 2.6-2 Dimensional Homogeneity and Dimensionless Groups (a) The Nernst equation is used to predict the voltage in a fuel cell as a function of the partial pressure of the gases. This formula can be rearranged to give: P,P2 H2 02 [2F(E-E,) Pu20 P2 RT If F has units of C/mol e', E and Eo have units of V, R has units of J/mol H,-K, and T has units of K, then what are the units on the constant 2? Strategy We can compare the prescribed units to determine the unknown units. Solution The term in the natural log must be dimensionless. Thus, noting that 1 V = 1 J/C, we can solve for the units on 2 as: J -K mol H, - K C J mole C RT mol F(E-E,) mol (b) A dimensionless group in heat transfer is the Prandtl number, given by: µC, Pr k
Example 2.6-2 Dimensional Homogeneity and Dimensionless Groups (a) The Nernst equation is used to predict the voltage in a fuel cell as a function of the partial pressure of the gases. This formula can be rearranged to give: P,P2 H2 02 [2F(E-E,) Pu20 P2 RT If F has units of C/mol e', E and Eo have units of V, R has units of J/mol H,-K, and T has units of K, then what are the units on the constant 2? Strategy We can compare the prescribed units to determine the unknown units. Solution The term in the natural log must be dimensionless. Thus, noting that 1 V = 1 J/C, we can solve for the units on 2 as: J -K mol H, - K C J mole C RT mol F(E-E,) mol (b) A dimensionless group in heat transfer is the Prandtl number, given by: µC, Pr k
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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