Ethanol, with AHvap = 40.5 kJ mol-1, has a higher AHvap than methanol, which is 35.2 kJ mol1, due to its larger size and greater intermolecular forces. Because the AHvap for ethanol is larger, we would expect that for the two liquids to reach the same vapor pressure, the temperature for ethanol would have to be higher. If the vapor pressure is 0.0992 atm at 27.3 °C, what would the temperature be when the vapor pressure is 8.53 atm? The temperature will be i 140 ! К.

Ethanol, with AHvap = 40.5 kJ mol-1, has a higher AHvap than methanol, which is 35.2 kJ mol1, due to its larger size and greater intermolecular forces. Because the AHvap for ethanol is larger, we would expect that for the two liquids to reach the same vapor pressure, the temperature for ethanol would have to be higher. If the vapor pressure is 0.0992 atm at 27.3 °C, what would the temperature be when the vapor pressure is 8.53 atm? The temperature will be i 140 ! К.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Ethanol, with ΔHvap = 40.5 kJ mol-1, has a higher ΔHvap than methanol, which is 35.2 kJ mol-1, due to its larger size and greater intermolecular forces. Because the ΔHvap for ethanol is larger, we would expect that for the two liquids to reach the same vapor pressure, the temperature for ethanol would have to be higher. If the vapor pressure is 0.0992 atm at 27.3 °C, what would the temperature be when the vapor pressure is 4.52 atm?
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