Ethanol, C₂H5OH, is used to introduce oxygen into some blends of gasoline. It has a heat of combustion of 1366.8 kJ/mol. What is the heat of formation of ethanol? Remember that the heat of formation of an element in its standard state will always be zero. C₂H5OH(e) + O₂(g) → CO₂(g) + H₂O(e); AH° = -1,366.8 kJ Other information: AHf [CO₂(9)] = -393.5 kJ/mol; AHf [H₂O()] = -285.8 kJ/mol O -278 kJ 278 J/mol O -277.6 kJ/mol 270 J
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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