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- Criteria for satisfactory score Reactants, products, and reagents that complete a reaction scheme must specific compounds, not generic categories. Reagents and structures must be valid Lewis structures. Tasks 1. Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below. 2. Draw the mechanism of tautomerization (line 3).(i) Substitution vs elimination: identify the major and minor products for each of the following reactions. Br (j) Br (k) Br NaOEt EtOH ? KOC(CH3)3 ? NaOMe ? (1) 10 f NaOH ?Complete the given reactions by drawing the structures of the major organic products: Please draw the completed reaction OH HO HOCN H₂N H₂O H3PO4 OH HO HO. (excess) H3O+ H2SO4 H*
- Complete the following reaction by determining the products: H3PO4 + 3KOH → ? O KH3SO5 O K3PO4 + 3H2O O KPO4 + H402 O K2PO4 + 2H2 + O25. Complete the reaction below: OH OCH3 + CH3IKetones and aldehydes react with sodium acetylide (the sodium salt of acetylene) to give alcohols, as shown in the following example: R OH 1. HC=C: Na* 2. H30* R2 Rí `R2 HC Draw the structure of the major reaction product when the following compound reacts with sodium acetylide, assuming that the reaction takes preferentially from the Re face of the carbonyl group. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. • If a group is achiral, do not use wedged or hashed bonds on it. H H3C H CH3
- Q3: Complete the following reactions: OCH3 NO2 AICI3 H3C- heat H2SO4 + Br2 CCI420:24 : ●●● E) 03 12. Fill in the box with the major organic product of the first step of the reaction shown? The first step of the reaction shown is an exhaustive methylation and is one of the SN2, SN1, E2, or E1 reactions. Another piece of information about this full reaction, the second step proceeds via an E2 mechanism. xs CH₂l 13. What is the name of the reaction in the previous question? A) Swern Oxidation Hofmann Elimination ABCD Ag₂O, A Cope Elimination Williamson Ether Synthesis Send a chat OOH KI, Oxone H₂O 22 °C, 1 hr Scheme 1: lodolactionization starting materials and reaction conditions
- What is the product of this reaction? с (A) ОН OH (В) 1. LiAlH4 2.H+ н ??? (C) ОН (D) ОН н6. Select the most hydrophobic (non-polar) aromatic compound that has the least water solubility. a) c) CH3 OH B b) с d) LOCH3 7. Select the electrophile in the following electrophilic aromatic substitution rea A CO₂H NO₂2) How might you prepare 2-phenylethanol from benzyl bromide? More than one step is needed. O 236 Sajjad Oday, 10:36 PM