Enter the precise mass numbers to the nearest 0.0001 mass unit. Compound A: C4H6O2 Compound B: C4H6S Precise mass of molecular ions: Compound A: Compound B: A laundoncog of Isotones Relati

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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[References]
Show how the compounds (A and B) presented below, both having a nominal mass of 86, can be distinguished by the m/z ratio of their molecular ions
in high resolution mass spectrometry. Use Table 14.2 to calculate the precise masses for each molecular ion and enter the corresponding numbers in
the boxes provided below.
Enter the precise mass numbers to the nearest 0.0001 mass unit.
Compound A: C4H6O2
Compound B: C,H6S
Precise mass of molecular ions:
Compound A:
Compound B:
Table 14.2: Precise Masses and Natural Abundances of Isotopes. Relative to 100
Atoms of the Most Abundant Isotope
Element
Atomic Weight Isotope Precise Mass (amu) Relative Abundance
Hydrogen 1.0079
1.00783
100
2H
2.01410
0.016
Carbon
12.011
12 C
12.0000
100
13 C
13.0034
1.11
Nitrogen
14.007
14N
14.0031
100
15 N
15.0001
0.38
160
15.9949
100
Oxygen
15.999
54%
h
Transcribed Image Text:[References] Show how the compounds (A and B) presented below, both having a nominal mass of 86, can be distinguished by the m/z ratio of their molecular ions in high resolution mass spectrometry. Use Table 14.2 to calculate the precise masses for each molecular ion and enter the corresponding numbers in the boxes provided below. Enter the precise mass numbers to the nearest 0.0001 mass unit. Compound A: C4H6O2 Compound B: C,H6S Precise mass of molecular ions: Compound A: Compound B: Table 14.2: Precise Masses and Natural Abundances of Isotopes. Relative to 100 Atoms of the Most Abundant Isotope Element Atomic Weight Isotope Precise Mass (amu) Relative Abundance Hydrogen 1.0079 1.00783 100 2H 2.01410 0.016 Carbon 12.011 12 C 12.0000 100 13 C 13.0034 1.11 Nitrogen 14.007 14N 14.0031 100 15 N 15.0001 0.38 160 15.9949 100 Oxygen 15.999 54% h
[References]
Table 14.2: Precise Masses and Natural Abundances of Isotopes. Relative to 100
Atoms of the Most Abundant Isotope
Element
Atomic Weight Isotope Precise Mass (amu) Relative Abundance
Hydrogen 1.0079
'H
1.00783
100
2H
2.01410
0.016
Carbon
12.011
12 C
12.0000
100
13 C
13.0034
1.11
Nitrogen
14.007
14N
14.0031
100
15 N
15.0001
0.38
Охygen
15.999
16 0
15.9949
100
17 0
16.9991
0.04
18 O
17.9992
0.20
Sulfur
32.066
32 S
31.9721
100
33 S
32.9715
0.78
34 S
33.9679
4.40
Chlorine
35.453
35 C1
34.9689
100
37 Cl
36.9659
31.98
Bromine
79.904
79 Br
78.918
100
81 Br
80.9163
98.0
Transcribed Image Text:[References] Table 14.2: Precise Masses and Natural Abundances of Isotopes. Relative to 100 Atoms of the Most Abundant Isotope Element Atomic Weight Isotope Precise Mass (amu) Relative Abundance Hydrogen 1.0079 'H 1.00783 100 2H 2.01410 0.016 Carbon 12.011 12 C 12.0000 100 13 C 13.0034 1.11 Nitrogen 14.007 14N 14.0031 100 15 N 15.0001 0.38 Охygen 15.999 16 0 15.9949 100 17 0 16.9991 0.04 18 O 17.9992 0.20 Sulfur 32.066 32 S 31.9721 100 33 S 32.9715 0.78 34 S 33.9679 4.40 Chlorine 35.453 35 C1 34.9689 100 37 Cl 36.9659 31.98 Bromine 79.904 79 Br 78.918 100 81 Br 80.9163 98.0
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