Elementary Steps – the "language" of reaction mechanisms!!! Proton transfer Nucleophilic addition H-A B-H + A:O Nu:O Nu Coordination Nucleophile elimination 美。 B:0 + O:L Abbreviation Legend: LG = leaving group Nu = nucleophile E = electrophile X = an electronegative Heterolysis atom Electrophilic addition RO O:LG Bimolecular nucleophilic substitution (SN2) Electrophile elimination Nu:O R- * Nu-R + O:LG + E Bimolecular elimination (E2) Carbocation rearrangemen H(R) H(R) B:0 H-C В-н + + O:LG Full Mechanism: H-o-SO3H H H-Ö -SO3H (or water) proton transfer O-H O: H H-O-SO;H (or H3o*) Regeneration of acid catalyst Ester product 1
Elementary Steps – the "language" of reaction mechanisms!!! Proton transfer Nucleophilic addition H-A B-H + A:O Nu:O Nu Coordination Nucleophile elimination 美。 B:0 + O:L Abbreviation Legend: LG = leaving group Nu = nucleophile E = electrophile X = an electronegative Heterolysis atom Electrophilic addition RO O:LG Bimolecular nucleophilic substitution (SN2) Electrophile elimination Nu:O R- * Nu-R + O:LG + E Bimolecular elimination (E2) Carbocation rearrangemen H(R) H(R) B:0 H-C В-н + + O:LG Full Mechanism: H-o-SO3H H H-Ö -SO3H (or water) proton transfer O-H O: H H-O-SO;H (or H3o*) Regeneration of acid catalyst Ester product 1
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can you please write out the mechanism in words? I'm having trouble writing mrchanisms in words so please please explain each step concisely, with proper mechanistic teminology.
Detailed explanation would be really great.. please help

Transcribed Image Text:Elementary Steps – the "language" of reaction
mechanisms!!!
Proton transfer
Nucleophilic addition
B-H + A:O
Nu:O
Nu
Coordination
Nucleophile elimination
上。
B:O
+ O:LG
Abbreviation Legend:
LG = leaving group
Nu = nucleophile
E = electrophile
X = an electronegative
Heterolysis
atom
Electrophilic addition
R-LG
RO
O:LG
Bimolecular nucleophilic substitution (S2)
Electrophile elimination
Nu-6 RiG
Nu-R + O:LG
Bimolecular elimination (E2)
Carbocation rearrangement
H(R)
H(R)
H-c
B-H +
+ O:LG
Full Mechanism:
.H
H-O-SO3H
H-Ö
-o3 (or water)
proton
transfer
O: H
H-o-so,H (or H30*)
Regeneration of acid catalyst
Ester product
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