Elemental sulfur is a yellow solid that consists of S8 molecules. The structure of the S8 molecule is a puckered, eightmemberedring (see Figure 7.27). Heating elemental sulfur to high temperatures produces gaseous S2 molecules:S81s2¡4 S21g2(a) The electron configuration of which period 2 element is most similar to that of sulfur? (b) Use the VSEPR model to predictthe S¬S¬S bond angles in S8 and the hybridization at S in S8. (c) Use MO theory to predict the sulfur–sulfur bondorder in S2. Do you expect this molecule to be diamagnetic or paramagnetic? (d) Use average bond enthalpies (Table 8.3) toestimate the enthalpy change for this reaction. Is the reaction exothermic or endothermic?

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Elemental sulfur is a yellow solid that consists of S8 molecules. The structure of the S8 molecule is a puckered, eightmembered
ring (see Figure 7.27). Heating elemental sulfur to high temperatures produces gaseous S2 molecules:
S81s2¡4 S21g2
(a) The electron configuration of which period 2 element is most similar to that of sulfur? (b) Use the VSEPR model to predict
the S¬S¬S bond angles in S8 and the hybridization at S in S8. (c) Use MO theory to predict the sulfur–sulfur bond
order in S2. Do you expect this molecule to be diamagnetic or paramagnetic? (d) Use average bond enthalpies (Table 8.3) to
estimate the enthalpy change for this reaction. Is the reaction exothermic or endothermic?

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