elect one: O a. False low pH readings at low sample pH values due to the positive interference of Na+ and other alkali cations on the potential (EMF) of the glass membrane O b. False low pH readings at very high sample pH values due to positive interference of Na+ and other alkali cations on the potential (EMF) of the glass membrane O c. False high pH reactings at low sample pH values due to the negative interference of Na+ and other alkali cations on the potential (EMF) of the glass membrane O d. False high pH readings at very high sample pH values due to positive interference of Nat and other alkali cations on the potential (EMF) of the glass membrane O e. Both false low and false high values depending on experimental setup

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
Clear my choice
Alkaline error associated with the use of glass membrane pH electrodes for pH measurements will yield:
Select one:
O a. False low pH readings at low sample pH values due to the positive interference of Na+ and other alkali cations on the potential
(EMF) of the glass membrane
cion
O b. False low pH readings at very high sample pH values due to positive interference of
Na+ and other alkali cations on the potential (EMF) of the glass membrane
O c. False high pH reactings at low sample pH values due te the negative interference of
Na+ and other alkali cations on the potential (EMF) of the glass membrane
O d. False high pH readings at very high sample pH values due to positive interference of
Na+ and other alkali cations on the potential (EMF) of the glass membrane
O e. Bath false low and false high values depending on experimental setup
Clear my choice
A Na ion-selective electrode increased in voltage by 59.16 mV when the sodium ion activity increased by a factor of 10. An S-¯ son-
selective electrode measured a decrease of 29.58 mV when the sulfide activvity increased by a factor of 10. Why?
I. For cations, the measured potential increases by a factor of a 59 16 mV for every 10-fold change in the activity of the cation
4
aved
Tume ef
it of
the charge on the cation
hy a factor of x 59.16 mV for every 10-fold change in the activity of the anian
Transcribed Image Text:Clear my choice Alkaline error associated with the use of glass membrane pH electrodes for pH measurements will yield: Select one: O a. False low pH readings at low sample pH values due to the positive interference of Na+ and other alkali cations on the potential (EMF) of the glass membrane cion O b. False low pH readings at very high sample pH values due to positive interference of Na+ and other alkali cations on the potential (EMF) of the glass membrane O c. False high pH reactings at low sample pH values due te the negative interference of Na+ and other alkali cations on the potential (EMF) of the glass membrane O d. False high pH readings at very high sample pH values due to positive interference of Na+ and other alkali cations on the potential (EMF) of the glass membrane O e. Bath false low and false high values depending on experimental setup Clear my choice A Na ion-selective electrode increased in voltage by 59.16 mV when the sodium ion activity increased by a factor of 10. An S-¯ son- selective electrode measured a decrease of 29.58 mV when the sulfide activvity increased by a factor of 10. Why? I. For cations, the measured potential increases by a factor of a 59 16 mV for every 10-fold change in the activity of the cation 4 aved Tume ef it of the charge on the cation hy a factor of x 59.16 mV for every 10-fold change in the activity of the anian
Expert Solution
steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemical-engineering and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The