eactivity? Does it just mean the ring cannot undergo a ring flip LIAIH4 tBu

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2. What is the effect of a tert-butyl group when placed in a 6 membered ring? I've been told it "locks" the conformation but I don't understand what that means exactly. Does it have an
effect on reactivity? Does it just mean the ring cannot undergo a ring flip? For example, in the reaction below would the ketone reduce to an alcohol as normal, as though the tBu group
LIAIH4
*tBu
wasn't there?
Transcribed Image Text:2. What is the effect of a tert-butyl group when placed in a 6 membered ring? I've been told it "locks" the conformation but I don't understand what that means exactly. Does it have an effect on reactivity? Does it just mean the ring cannot undergo a ring flip? For example, in the reaction below would the ketone reduce to an alcohol as normal, as though the tBu group LIAIH4 *tBu wasn't there?
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