**Question E: Ranking of Benzene Derivatives by Activation and Directive Properties****Objective:** Rank the following molecules in decreasing order of activation (from most activated, assigned a rank of 1, to most deactivated, assigned a rank of 6) based on the substituents present on the benzene ring. Also, indicate whether the substituents are ortho-para or meta directors.**Molecules Provided:**1. **Molecule A:** Benzoic acid (benzene ring with a carboxyl group, -COOH)2. **Molecule B:** Isopropylbenzene (benzene ring with an isopropyl group, -CH(CH₃)₂)3. **Molecule C:** Nitrobenzene (benzene ring with a nitro group, -NO₂)4. **Molecule D:** Aniline (benzene ring with an amino group, -NH₂)5. **Molecule E:** Chlorobenzene (benzene ring with a chloro group, -Cl)6. **Molecule F:** Benzyl acetate (benzene ring with an acetoxy group, -OCOCH₃)**Instructions for Ranking and Directive Properties:**- **Activation trend:** The activation or deactivation of the benzene ring depends on the substituent’s electronic effects. Electron-donating groups (EDGs) activate the ring, whereas electron-withdrawing groups (EWGs) deactivate the ring.- **Directive properties:** Substituents can be either ortho-para directors (EDGs usually) or meta directors (EWGs usually).**Analyzed Details:**1. **Aniline (-NH₂):** - **Activation:** Strong electron-donating group. - **Directive Property:** Ortho-para director. - **Rank:** 1 (most activated).2. **Isopropylbenzene (-CH(CH₃)₂):** - **Activation:** Moderately electron-donating group. - **Directive Property:** Ortho-para director. - **Rank:** 2.3. **Chlorobenzene (-Cl):** - **Activation:** Weakly deactivating group (due to inductive withdrawal but resonance donation). - **Directive Property:** Ortho-para director. - **Rank:** 3.4. **Benzoic acid (-COOH):**

The groups which activates the benzene ring should have +M effect or that can donates the electron…

E. Rank the following molecules in decreasing activation (from most activated =1 to most deactivated =6) based on the substituents present on the benzene ring. Also indicate whether the substituents are ortho-para or meta directors. HO -NH₂ CI

E. Rank the following molecules in decreasing activation (from most activated =1 to most deactivated =6) based on the substituents present on the benzene ring. Also indicate whether the substituents are ortho-para or meta directors. HO -NH₂ CI

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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