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e. f. Br NaH SH 1. PBr3 2. Mg, thf 3. Ethylene oxide 4. H₂O/H3O+ Label step 3 only OH

e. f. Br NaH SH 1. PBr3 2. Mg, thf 3. Ethylene oxide 4. H₂O/H3O+ Label step 3 only OH

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Transcription for Educational Website #### Reaction Scheme Analysis ##### Reaction e: 1. **Initial Reagents:** - \( \text{PBr}_3 \) - \( \text{Mg, THF} \) 2. **Intermediate Reaction:** - **Step 3:** The compound reacts with Ethylene oxide. 3. **Final Step:** - **Step 4:** Reaction occurs in the presence of \( \text{H}_2\text{O/H}_3\text{O}^+ \). 4. **Product:** The reaction sequence results in a compound with a primary alcohol group attached to a carbon chain. ##### Reaction f: 1. **Initial Compound:** A brominated alkane is used as the starting material. 2. **Reagents:** - \( \text{NaH} \) - \( \text{SH} \) 3. **Reaction Pathway:** The bromine atom is replaced, resulting in a substitution reaction where the thiolate ion from \( \text{SH} \) acts as a nucleophile, leading to the formation of a new thioether compound. Each reaction pathway highlights specific reagents and conditions involved in the transformation, showcasing crucial understanding points for students studying organic synthesis processes.
Transcribed Image Text:### Transcription for Educational Website #### Reaction Scheme Analysis ##### Reaction e: 1. **Initial Reagents:** - \( \text{PBr}_3 \) - \( \text{Mg, THF} \) 2. **Intermediate Reaction:** - **Step 3:** The compound reacts with Ethylene oxide. 3. **Final Step:** - **Step 4:** Reaction occurs in the presence of \( \text{H}_2\text{O/H}_3\text{O}^+ \). 4. **Product:** The reaction sequence results in a compound with a primary alcohol group attached to a carbon chain. ##### Reaction f: 1. **Initial Compound:** A brominated alkane is used as the starting material. 2. **Reagents:** - \( \text{NaH} \) - \( \text{SH} \) 3. **Reaction Pathway:** The bromine atom is replaced, resulting in a substitution reaction where the thiolate ion from \( \text{SH} \) acts as a nucleophile, leading to the formation of a new thioether compound. Each reaction pathway highlights specific reagents and conditions involved in the transformation, showcasing crucial understanding points for students studying organic synthesis processes.
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