E + PV E - PV -E + PV ΔΕ + Δ(PV) ΔΕ – Δ(PV) -ΔΕ – Δ(PV) RΤΔη -RΤΔη According to the definition of enthalpy, H = so ΔΗ = gas at constant temperature and volume, Δ(PV) = VΔΡ = Thus VAP or A (PV) is A(PV) term means that AE is larger than AH. is Because AH = For an ideal For this reaction, Δη the

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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E + PV
E - PV
-E + PV
AE+A(PV)
AE - A(PV)
-AE-A(PV)
RT Δη
-RTAn
positive
negative
According to the definition of enthalpy, H
gas at constant temperature and volume, A(PV) = VAP =
Thus VAP or A(PV) is
Δ(PV) term means that ΔΕ is larger than ΔΗ.
, so ΔΗ –
IS
Because ΔΗ
Reset Help
. For an ideal
. For this reaction, An
, the
Transcribed Image Text:E + PV E - PV -E + PV AE+A(PV) AE - A(PV) -AE-A(PV) RT Δη -RTAn positive negative According to the definition of enthalpy, H gas at constant temperature and volume, A(PV) = VAP = Thus VAP or A(PV) is Δ(PV) term means that ΔΕ is larger than ΔΗ. , so ΔΗ – IS Because ΔΗ Reset Help . For an ideal . For this reaction, An , the
Suppose that the gas-phase reaction
2 NO(g) + O₂(g) →2 NO₂ (g) were carried out in a constant-
volume container at constant temperature.
Transcribed Image Text:Suppose that the gas-phase reaction 2 NO(g) + O₂(g) →2 NO₂ (g) were carried out in a constant- volume container at constant temperature.
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