Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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What are the products from the following reactions? Please help with part e,f,g
![The image contains handwritten notes detailing various organic chemistry reactions. Here is a transcription of each reaction, along with explanations:
**a)**
- Structure: CH₃-CH₂-N-CH₃ with a lone pair on nitrogen.
- Reaction: H₂O, heat
- Description: The reaction of a tertiary amine with water under heat conditions.
**b)**
- Structure: Benzene ring with a carboxylic acid group (C=O) attached.
- Reaction: Heated with ethanol (EtOH) and catalytic HCl.
- Description: This represents the Fischer esterification process to form an ester from a carboxylic acid and alcohol.
**c)**
- Structure: A five-membered ring with an oxygen (cyclic ester, possibly lactone).
- Reaction: Heated with CH₃OH (methanol) and an acid catalyst.
- Description: Alcoholysis of a lactone to form a linear ester.
**d)**
- Structure: Ethyl benzoate.
- Reaction: Excess isopropanol, HCl
- Description: Transesterification process where an ester reacts with an alcohol in the presence of acid to form a new ester.
**e)**
- Structure: Chemical reaction involving an aromatic chloride and an amine.
- Reaction: CH₃(CH₂)₂NH₂ (excess)
- Description: A nucleophilic substitution where an amine replaces the chlorine atom in an aromatic chloride.
**f)**
- Structure: Cyclic ether (epoxide).
- Reaction: Undergoes reaction with HCl in H₂O.
- Description: Acid-catalyzed opening of an epoxide ring with water.
**g)**
- Structure: Benzene ring bonded to a CO₂CH₃ group (ester).
- Reaction: Unspecified
- Description: Involves a benzene derivative with an ester functional group.
**h)**
- Structure: Cyclohexanol and a benzene ring with an attached acyl chloride group.
- Reaction: Acyclic reaction to form an ester or amide.
- Description: Alcohol reacting with an acyl chloride to form an ester or an amine reacting to form an amide.
These notes illustrate various reactions involved in organic synthesis, focusing on transformations like esterification, transesterification, and nucleophilic substitutions.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0d37489c-b06e-4663-91d7-ac16cfad329d%2F2ca818b7-990a-4e39-ae3c-98ca2e03ca94%2Fm0w79wr_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The image contains handwritten notes detailing various organic chemistry reactions. Here is a transcription of each reaction, along with explanations:
**a)**
- Structure: CH₃-CH₂-N-CH₃ with a lone pair on nitrogen.
- Reaction: H₂O, heat
- Description: The reaction of a tertiary amine with water under heat conditions.
**b)**
- Structure: Benzene ring with a carboxylic acid group (C=O) attached.
- Reaction: Heated with ethanol (EtOH) and catalytic HCl.
- Description: This represents the Fischer esterification process to form an ester from a carboxylic acid and alcohol.
**c)**
- Structure: A five-membered ring with an oxygen (cyclic ester, possibly lactone).
- Reaction: Heated with CH₃OH (methanol) and an acid catalyst.
- Description: Alcoholysis of a lactone to form a linear ester.
**d)**
- Structure: Ethyl benzoate.
- Reaction: Excess isopropanol, HCl
- Description: Transesterification process where an ester reacts with an alcohol in the presence of acid to form a new ester.
**e)**
- Structure: Chemical reaction involving an aromatic chloride and an amine.
- Reaction: CH₃(CH₂)₂NH₂ (excess)
- Description: A nucleophilic substitution where an amine replaces the chlorine atom in an aromatic chloride.
**f)**
- Structure: Cyclic ether (epoxide).
- Reaction: Undergoes reaction with HCl in H₂O.
- Description: Acid-catalyzed opening of an epoxide ring with water.
**g)**
- Structure: Benzene ring bonded to a CO₂CH₃ group (ester).
- Reaction: Unspecified
- Description: Involves a benzene derivative with an ester functional group.
**h)**
- Structure: Cyclohexanol and a benzene ring with an attached acyl chloride group.
- Reaction: Acyclic reaction to form an ester or amide.
- Description: Alcohol reacting with an acyl chloride to form an ester or an amine reacting to form an amide.
These notes illustrate various reactions involved in organic synthesis, focusing on transformations like esterification, transesterification, and nucleophilic substitutions.
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