Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter13: Acids And Bases
Section: Chapter Questions
Problem 58QAP: Consider citric acid, H3C6H5O7, added to many soft drinks. The equilibrium constants for its...
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![S 16.95 In the vapor phase, acetic acid molecules associate to
a certain extent to form dimers:
2CH;COOH(g) – (CH,COOH),(g)
At 51°C, the pressure of a certain acetic acid vapor
system is 0.0342 atm in a 360-mL flask. The vapor is
condensed and neutralized with 13.8 mL of 0.0568 M
NaOH. (a) Calculate the degree of dissociation (a) of
the dimer under these conditions:
(CH-COОH)2 2CH,СООН
(Hint: See Problem 15.65 for general procedure.)
(b) Calculate the equilibrium constant Kp for the
reaction in (a).](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F48e8aad0-5abb-4cde-9ad9-348e1b070922%2F1482562b-d8e7-4e02-9656-c103760c764e%2Fz24gttb_processed.jpeg&w=3840&q=75)
Transcribed Image Text:S 16.95 In the vapor phase, acetic acid molecules associate to
a certain extent to form dimers:
2CH;COOH(g) – (CH,COOH),(g)
At 51°C, the pressure of a certain acetic acid vapor
system is 0.0342 atm in a 360-mL flask. The vapor is
condensed and neutralized with 13.8 mL of 0.0568 M
NaOH. (a) Calculate the degree of dissociation (a) of
the dimer under these conditions:
(CH-COОH)2 2CH,СООН
(Hint: See Problem 15.65 for general procedure.)
(b) Calculate the equilibrium constant Kp for the
reaction in (a).
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