Organic Chemistry 9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: John E. McMurry
1 Structure And Bonding 2 Polar Covalent Bonds; Acids And Bases 3 Organic Compounds: Alkanes And Their Stereochemistry 4 Organic Compounds: Cycloalkanes And Their Stereochemistry 5 Stereochemistry At Tetrahedral Centers 6 An Overview Of Organic Reactions 7 Alkenes: Structure And Reactivity 8 Alkenes: Reactions And Synthesis 9 Alkynes: An Introduction To Organic Synthesis 10 Organohalides 11 Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations 12 Structure Determination: Mass Spectrometry And Infrared Spectroscopy 13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy 14 Conjugated Compounds And Ultraviolet Spectroscopy 15 Benzene And Aromaticity 16 Chemistry Of Benzene: Electrophilic Aromatic Substitution 17 Alcohols And Phenols 18 Ethers And Epoxides; Thiols And Sulfides 19 Aldehydes And Ketones: Nucleophilic Addition Reactions 20 Carboxylic Acids And Nitriles 21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions 22 Carbonyl Alpha-substitution Reactions 23 Carbonyl Condensation Reactions 24 Amines And Heterocycles 25 Biomolecules: Carbohydrates 26 Biomolecules: Amino Acids, Peptides, And Proteins 27 Biomolecules: Lipids 28 Biomolecules: Nucleic Acids 29 The Organic Chemistry Of Metabolic Pathways 30 Orbitals And Organic Chemistry: Pericyclic Reactions 31 Synthetic Polymers Chapter10: Organohalides
10.1 Names And Structures Of Alkyl Halides 10.2 Preparing Alkyl Halides From Alkanes: Radical Halogenation 10.3 Preparing Alkyl Halides From Alkenes: Allylic Bromination 10.4 Stability Of The Allyl Radical: Resonance Revisited 10.5 Preparing Alkyl Halides From Alcohols 10.6 Reactions Of Alkyl Halides: Grignard Reagents 10.7 Organometallic Coupling Reactions 10.8 Oxidation And Reduction In Organic Chemistry 10.SE Something Extra Section10.SE: Something Extra
Problem 14VC Problem 15VC Problem 16VC Problem 17MP: Draw the electron-pushing mechanism for each radical reaction below. Identify each step as... Problem 18MP: Draw the electron-pushing mechanism for the propagation steps of the allylic bromination reactions... Problem 19MP: The formation of Br2 from NBS first involves the reaction of NBS with HBr to form an iminol... Problem 20MP: In light of the fact that tertiary alkyl halides undergo spontaneous dissociation to yield a... Problem 21MP: Alkyl halides can be reduced to alkanes by a radical reaction with tributyltin hydride, (C4H9)3SnH,... Problem 22AP: Name the following alkyl halides: Problem 23AP Problem 24AP: Draw and name all of the monochlorination products that you might obtain from the radical... Problem 25AP: How would you prepare the following compounds, starting with cyclopentene and any other reagents... Problem 26AP Problem 27AP: A chemist requires a large amount of 1-bromo-2-pentene as starting material for a synthesis and... Problem 28AP: What product(s) would you expect from the reaction of 1-methylcyclohexene with NBS? Would you use... Problem 29AP: What product(s) would you expect from the reaction of 1,4-hexadiene with NBS? What is the structure... Problem 30AP: What product would you expect from the reaction of 1-phenyl-2-butene with NBS? Explain. Problem 31AP: Rank the compounds in each of the following series in order of increasing oxidation level: Problem 32AP: Which of the following compounds have the same oxidation level, and which have different levels? Problem 33AP: Tell whether each of the following reactions is an oxidation, a reduction, or neither: Problem 34AP Problem 35AP: Alkylbenzenes such as toluene (methylbenzene) react with NBS to give products in which bromine... Problem 36AP Problem 37AP Problem 38AP Problem 39AP Problem 40AP Problem 41AP: The syntheses shown here are unlikely to occur as written. What is wrong with each? Problem 42AP: Why do you suppose its not possible to prepare a Grignard reagent from a bromo alcohol such as... Problem 43AP Problem 44AP: Identify the reagents a–c in the following scheme: Problem 45AP Problem 46AP Problem 47AP Problem 48AP: The relative rate of radical bromination is 1;82;1640 for 1;2;3 hydrogens, respectively. Draw all of... Problem 49AP Problem 50AP: Predict the product and provide the entire catalytic cycle for the Suzuki–Miyaura reactions below. Problem 23AP
Related questions
Draw the structural diagram for the following:
1. 6, 7-dimethylnona-2,4-diene
2. 2,2-dichloro-4-iodoheptane-3,5-diol
3. 5-fluoro-4-propylbenzene-1,3-diol
Definition Definition Chemical compound containing two hydroxyl ( - OH ) groups. When naming such compounds, the suffix -diol is added to the name of parent chain alkane.
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