Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Title: Radical Polymerization and Starting Structures**
---
**Objective:**
To understand the process of radical polymerization by identifying the starting structure that leads to a given polymer.
---
**Instructions:**
"Draw the starting structure that would lead to this polymer under radical conditions."
---
**Diagram Description:**
1. There is a dashed box, indicating that a starting structure needs to be drawn here.
2. An arrow labeled with "Δ or 2V, AIBN/radical initiator" points downward, suggesting the transformation process.
3. Below the arrow, there is a structural diagram of a polymer. It shows repeating units with ‘Cl’ (chlorine) attached to a carbon backbone, labeled as "n" to indicate the repeating nature of the polymer chain.
---
**Explanation of the Diagram:**
- **Dashed Box:** Represents the area where the monomer structure should be drawn. In radical polymerization, this is typically the vinyl monomer.
- **Arrow Specifications:**
- "Δ or 2V": Implies the use of heat (Δ) or another energy source (2V) to initiate the reaction.
- "AIBN/radical initiator": Indicates the use of Azobisisobutyronitrile or a similar radical initiator to start the polymerization process.
- **Polymer Structure:**
- Repeating unit with chlorine atoms attached.
- Represented in a linear fashion with 'n' indicating the number of repeating units in the chain.
---
**Conclusion:**
Understanding the initial structures and conditions required for radical polymerization enables the creation of polymers with desired properties. The correct monomer must be drawn in the placeholder for successful synthesis under specified conditions.
---](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F43e6dec2-76df-4940-9249-0e7480f29688%2F2f55db8c-17fa-4b52-9950-6ff79e3f5241%2Ftxo71b.jpeg&w=3840&q=75)
Transcribed Image Text:**Title: Radical Polymerization and Starting Structures**
---
**Objective:**
To understand the process of radical polymerization by identifying the starting structure that leads to a given polymer.
---
**Instructions:**
"Draw the starting structure that would lead to this polymer under radical conditions."
---
**Diagram Description:**
1. There is a dashed box, indicating that a starting structure needs to be drawn here.
2. An arrow labeled with "Δ or 2V, AIBN/radical initiator" points downward, suggesting the transformation process.
3. Below the arrow, there is a structural diagram of a polymer. It shows repeating units with ‘Cl’ (chlorine) attached to a carbon backbone, labeled as "n" to indicate the repeating nature of the polymer chain.
---
**Explanation of the Diagram:**
- **Dashed Box:** Represents the area where the monomer structure should be drawn. In radical polymerization, this is typically the vinyl monomer.
- **Arrow Specifications:**
- "Δ or 2V": Implies the use of heat (Δ) or another energy source (2V) to initiate the reaction.
- "AIBN/radical initiator": Indicates the use of Azobisisobutyronitrile or a similar radical initiator to start the polymerization process.
- **Polymer Structure:**
- Repeating unit with chlorine atoms attached.
- Represented in a linear fashion with 'n' indicating the number of repeating units in the chain.
---
**Conclusion:**
Understanding the initial structures and conditions required for radical polymerization enables the creation of polymers with desired properties. The correct monomer must be drawn in the placeholder for successful synthesis under specified conditions.
---
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