Draw the organic product(s) of the following reaction. CH3 H₂C-CH-C=C-H KO-t-Bu/t-BuOH

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-H
bonds react at relative rates of 1:3.9: 5.2 respectively.
These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B,
the A:B product ratio will be 2.
Consider chlorination of the alkane below at 35 °C.
1. Specify the most reactive C-H bond(s), a-c.
Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, i.e. a,c.
2. Specify the site of chlorination in the major monochloro substitution product, a-c.
Two products that form in comparable quantities should be separated by commas, i.e. a,c
Transcribed Image Text:In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-H bonds react at relative rates of 1:3.9: 5.2 respectively. These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B, the A:B product ratio will be 2. Consider chlorination of the alkane below at 35 °C. 1. Specify the most reactive C-H bond(s), a-c. Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, i.e. a,c. 2. Specify the site of chlorination in the major monochloro substitution product, a-c. Two products that form in comparable quantities should be separated by commas, i.e. a,c
Draw the organic product(s) of the following reaction.
CH3
H₂C-CH-C=C-H
KO-t-Bu/t-BuOH
Transcribed Image Text:Draw the organic product(s) of the following reaction. CH3 H₂C-CH-C=C-H KO-t-Bu/t-BuOH
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