In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-Hbonds react at relative rates of 1:3.9: 5.2 respectively.These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B,the A:B product ratio will be 2.Consider chlorination of the alkane below at 35 °C.1. Specify the most reactive C-H bond(s), a-c.Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, i.e. a,c.2. Specify the site of chlorination in the major monochloro substitution product, a-c.Two products that form in comparable quantities should be separated by commas, i.e. a,c Draw the organic product(s) of the following reaction.CH3H₂C-CH-C=C-HKO-t-Bu/t-BuOH

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Draw the organic product(s) of the following reaction. CH3 H₂C-CH-C=C-H KO-t-Bu/t-BuOH

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-H
bonds react at relative rates of 1:3.9: 5.2 respectively.
These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B,
the A:B product ratio will be 2.
Consider chlorination of the alkane below at 35 °C.
1. Specify the most reactive C-H bond(s), a-c.
Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, i.e. a,c.
2. Specify the site of chlorination in the major monochloro substitution product, a-c.
Two products that form in comparable quantities should be separated by commas, i.e. a,c

Draw the organic product(s) of the following reaction.
CH3
H₂C-CH-C=C-H
KO-t-Bu/t-BuOH

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