Draw the molecular orbital diagram for octahedral SF. Treat each F ligand as though it is spherically symmetric (like an H atom) to construct your SALCS. Mix these SALCS (which can start at -20 eV) with the valence s and p orbitals of sulfur (which have energies of -20.7 and -11.6 eV, respectively). Populate your diagram with 12 electrons (S has six valence e and each F interacts through one valence e). Label o, o, and nonbonding M.O.s. Use your diagram to suggest how a molecule can be hypervalent (i.e. contain a main group element that exceeds the octet rule) but still stable.
Draw the molecular orbital diagram for octahedral SF. Treat each F ligand as though it is spherically symmetric (like an H atom) to construct your SALCS. Mix these SALCS (which can start at -20 eV) with the valence s and p orbitals of sulfur (which have energies of -20.7 and -11.6 eV, respectively). Populate your diagram with 12 electrons (S has six valence e and each F interacts through one valence e). Label o, o, and nonbonding M.O.s. Use your diagram to suggest how a molecule can be hypervalent (i.e. contain a main group element that exceeds the octet rule) but still stable.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:3. Draw the molecular orbital diagram for octahedral SFs. Treat each F ligand as though it is
spherically symmetric (like an H atom) to construct your SALCS. Mix these SALCs (which can
start at -20 eV) with the valence s and p orbitals of sulfur (which have energies of -20.7 and
-11.6 eV, respectively). Populate your diagram with 12 electrons (S has six valence e and
each F interacts through one valence e). Label o, o, and nonbonding M.O.s. Use your
diagram to suggest how a molecule can be hypervalent (i.e. contain a main group element
that exceeds the octet rule) but still stable.
2
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