Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Question 6
![1- Write Walden's Cycle of Reactions Interconverting.
2- Mention the product of a nucleophilic substitution reaction of (S)-2-
bromohexane with acetate ion, CH3CO2-
Assume that inversion of configuration occurs, and show the chemistry
of both the reactant and product.
3- Draw the mechanism of the SN2 Reaction. Show the correct directions
of the arrows, and all reagents.
4- Draw the mechanism of the SN1 Reaction. Show the correct directions
of the arrows, and all reagents.
5- Draw the mechanism of the E2 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
6- Draw the mechanism of the E1 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
7- Mention the product formed in an SÃ2 reaction between 1-
bromobutane and Nal.
8- Rank the following compounds in order of their expected reactivity
toward SN2 reaction: CH3Br, CH3OT0s, (CH3)2CHCI.
9- Explain Grignard Reagents in details with one example.
10-
Mention how a halogen substituent can be replaced by a
deuterium atom in the preparation of a deuterated compound.
Br
D
|
CH3CHCH₂CH3
?
CH3CHCH₂CH3](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F389450d8-f111-499a-811c-3e6b049ffcf7%2Fff8b02f9-26b3-49bf-b587-cc59aa9f8ab4%2Fwig8pw9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1- Write Walden's Cycle of Reactions Interconverting.
2- Mention the product of a nucleophilic substitution reaction of (S)-2-
bromohexane with acetate ion, CH3CO2-
Assume that inversion of configuration occurs, and show the chemistry
of both the reactant and product.
3- Draw the mechanism of the SN2 Reaction. Show the correct directions
of the arrows, and all reagents.
4- Draw the mechanism of the SN1 Reaction. Show the correct directions
of the arrows, and all reagents.
5- Draw the mechanism of the E2 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
6- Draw the mechanism of the E1 Reaction with an Alkyl Halide. Show
the correct directions of the arrows, and all reagents.
7- Mention the product formed in an SÃ2 reaction between 1-
bromobutane and Nal.
8- Rank the following compounds in order of their expected reactivity
toward SN2 reaction: CH3Br, CH3OT0s, (CH3)2CHCI.
9- Explain Grignard Reagents in details with one example.
10-
Mention how a halogen substituent can be replaced by a
deuterium atom in the preparation of a deuterated compound.
Br
D
|
CH3CHCH₂CH3
?
CH3CHCH₂CH3
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