Draw the major product of this reaction. Ignore inorganic byproducts and the alkoxide side product. or N H 1. excess LIAIH4 2. H₂O

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

#28 help

**Instruction:**

Draw the major product of the reaction. Ignore inorganic byproducts and the alkoxide side product.

**Reaction Details:**

1. **Starting Compound:** A cyclic amide structure is provided, specifically, a caprolactam. The molecule consists of a 6-membered ring with an amide linkage (C=O connected to NH).

2. **Reagents:**
   - Step 1: Excess LiAlH₄ (Lithium aluminum hydride)
   - Step 2: H₂O (Water)

**Reaction Pathway:**

LiAlH₄ is a strong reducing agent typically used to reduce amides to amines. When a cyclic lactam like caprolactam is treated with LiAlH₄, it is expected to reduce the amide group to a secondary amine without breaking the ring structure.

**Outcome:**

The reaction should convert the amide group (C=O) to a methylene (CH₂) linked to nitrogen, resulting in a ring with a secondary amine.

**Drawing:**

A placeholder is provided indicating where the drawing of the product should go.
Transcribed Image Text:**Instruction:** Draw the major product of the reaction. Ignore inorganic byproducts and the alkoxide side product. **Reaction Details:** 1. **Starting Compound:** A cyclic amide structure is provided, specifically, a caprolactam. The molecule consists of a 6-membered ring with an amide linkage (C=O connected to NH). 2. **Reagents:** - Step 1: Excess LiAlH₄ (Lithium aluminum hydride) - Step 2: H₂O (Water) **Reaction Pathway:** LiAlH₄ is a strong reducing agent typically used to reduce amides to amines. When a cyclic lactam like caprolactam is treated with LiAlH₄, it is expected to reduce the amide group to a secondary amine without breaking the ring structure. **Outcome:** The reaction should convert the amide group (C=O) to a methylene (CH₂) linked to nitrogen, resulting in a ring with a secondary amine. **Drawing:** A placeholder is provided indicating where the drawing of the product should go.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 1 images

Blurred answer
Knowledge Booster
Alkanes and Cycloalkanes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY