Draw the major organic products for the following reactions; must include correct stereochemistry; double-dagger must show two products. Please can you answer all of them on the worksheet
Draw the major organic products for the following reactions; must include correct stereochemistry; double-dagger must show two products. Please can you answer all of them on the worksheet
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the major organic products for the following reactions; must include correct stereochemistry; double-dagger must show two products. Please can you answer all of them on the worksheet
![Professor
[H']/ HEAT
H20 (excess)
(k)
As
1)
1 M BH, in THF
+22 °C/1h
2) 3 M NAOH (aq.) / 30% H,O2
[Na*/-OOH] /30-50 °C/1h
[a] =-18.6°
(1)*
B-pinene
(73% yield)
BH, in THF
0 °C/2 h
(m)*
(3.0 equiv.)
BH, in THF
O °C/2h
(n) (3.0 equiv.)
BH, in THF
0°C/2 h
1)
2) 0°C/3M NaОН (ад)
30% H,O,/1 h
[Na*/-OOH]
H. C. Brown. JACS, 1959, 81, 247. (85 % yield)
(0)*
1) BH3
2) NaOH / H,0
H202
(p)*
1)
BH3-THF
2) NaOH / H2O2
[HOO-/ Na]
(q)
1) вн,-THF
2) NaOH/ H2O2
[HOO/ Na*1
(r)*
1) ВН,
2) NaOH / H2O
H,02
(s)*
1) BH3
2) NaOH / H,0
H2O2
(t)*](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F520467ac-d488-4216-a392-609cb0d88236%2F0cdbe629-c615-4765-859a-5ce5043c3ea9%2Fgus8z29_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Professor
[H']/ HEAT
H20 (excess)
(k)
As
1)
1 M BH, in THF
+22 °C/1h
2) 3 M NAOH (aq.) / 30% H,O2
[Na*/-OOH] /30-50 °C/1h
[a] =-18.6°
(1)*
B-pinene
(73% yield)
BH, in THF
0 °C/2 h
(m)*
(3.0 equiv.)
BH, in THF
O °C/2h
(n) (3.0 equiv.)
BH, in THF
0°C/2 h
1)
2) 0°C/3M NaОН (ад)
30% H,O,/1 h
[Na*/-OOH]
H. C. Brown. JACS, 1959, 81, 247. (85 % yield)
(0)*
1) BH3
2) NaOH / H,0
H202
(p)*
1)
BH3-THF
2) NaOH / H2O2
[HOO-/ Na]
(q)
1) вн,-THF
2) NaOH/ H2O2
[HOO/ Na*1
(r)*
1) ВН,
2) NaOH / H2O
H,02
(s)*
1) BH3
2) NaOH / H,0
H2O2
(t)*
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