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Draw the detailed mechanism and predict the major product of each of the following reactions. O₂N. F NO₂ NO₂ Br NaOH CH3NH2 (excess)

Draw the detailed mechanism and predict the major product of each of the following reactions. O₂N. F NO₂ NO₂ Br NaOH CH3NH2 (excess)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please explain every step the last expert did not answer the second part at all and the first part was incomplete.

The image presents two chemical reactions and prompts you to draw the detailed mechanism and predict the major product for each. 1. **Reaction 1:** - **Reactant:** A benzene ring with a fluorine (F) at the para position to an iodine (I), and two nitro groups (NO₂) at the ortho positions to the iodine. - **Reagent:** NaOH (sodium hydroxide) - **Process:** The reaction involves nucleophilic substitution, likely addressing the replacement or transformation of one of the groups on the aromatic ring, influenced by the presence of NaOH. 2. **Reaction 2:** - **Reactant:** A benzene ring with a chlorine (Cl) and nitro group (NO₂) at the ortho positions, and a bromine (Br) at the meta position relative to the chlorine. - **Reagent:** CH₃NH₂ (methylamine) in excess - **Process:** The reaction likely involves nucleophilic aromatic substitution where methylamine may replace one of the halogens due to the electron-withdrawing effect of the nitro group, facilitating substitution. **Task:** Analyze and draw the mechanism for each reaction step by step, considering the orientation effects and electronic interactions in the substitutions, and determine the major product formed in each case.
Transcribed Image Text:The image presents two chemical reactions and prompts you to draw the detailed mechanism and predict the major product for each. 1. **Reaction 1:** - **Reactant:** A benzene ring with a fluorine (F) at the para position to an iodine (I), and two nitro groups (NO₂) at the ortho positions to the iodine. - **Reagent:** NaOH (sodium hydroxide) - **Process:** The reaction involves nucleophilic substitution, likely addressing the replacement or transformation of one of the groups on the aromatic ring, influenced by the presence of NaOH. 2. **Reaction 2:** - **Reactant:** A benzene ring with a chlorine (Cl) and nitro group (NO₂) at the ortho positions, and a bromine (Br) at the meta position relative to the chlorine. - **Reagent:** CH₃NH₂ (methylamine) in excess - **Process:** The reaction likely involves nucleophilic aromatic substitution where methylamine may replace one of the halogens due to the electron-withdrawing effect of the nitro group, facilitating substitution. **Task:** Analyze and draw the mechanism for each reaction step by step, considering the orientation effects and electronic interactions in the substitutions, and determine the major product formed in each case.
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