Draw structural formulas for the alkoxide ion and the alkyl(aryl)bromide that may be used in a Williamson synthesisof the ether shown.CH3CH3CH₂-O-CCH₂CH3CH3You do not have to consider stereochemistry.• Do not include counter-ions, e.g., Na*, I, in your answer.Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right****corner.Separate structures with + signs from the drop-down menu./n [F

Alkyl bromide reacts with alkoxide ions to form an ether. The reaction is proceeded by the…

Answered: Draw structural formulas for the…

Draw structural formulas for the alkoxide ion and the alkyl(aryl)bromide that may be used in a Williamson synthesis of the ether shown. CH3 I CH3CH₂-O-CCH₂CH3 CH3

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 13E

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Concept explainers

Reactions of Ethers

Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.

Epoxides

Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.

Williamson Ether Synthesis

An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.

Question

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Draw structural formulas for the alkoxide ion and the alkyl(aryl)bromide that may be used in a Williamson synthesis
of the ether shown.
CH3
CH3CH₂-O-CCH₂CH3
CH3
You do not have to consider stereochemistry.
• Do not include counter-ions, e.g., Na*, I, in your answer.
Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right
****
corner.
Separate structures with + signs from the drop-down menu.
/n [F

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