Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter9: Nucleophilic Substitution And Β-elimination
Section: Chapter Questions
Problem 9.60P: Another important pattern in organic synthesis is the construction of CC bonds. Using your reaction...
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Question
![Draw a structural formula for the missing product in the following reaction.
(1) LIAIH4, ether
2 + LIOH + Al(OH)3
HČOH
(2) H20
Draw a structural formula for the missing organic product in the reaction below.
+ CH3OH
? + H,O
Draw a structural formula for the major organic product in the following:
(1) LIAIH, ether
2 + LIOH + Al(OH)3
HO,
(2) H20](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6cd0ba54-9c2f-4092-9f6d-bd36e9a12b87%2Fac0080ca-5229-4548-88a3-db49ceeb3075%2F5xh13z4_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Draw a structural formula for the missing product in the following reaction.
(1) LIAIH4, ether
2 + LIOH + Al(OH)3
HČOH
(2) H20
Draw a structural formula for the missing organic product in the reaction below.
+ CH3OH
? + H,O
Draw a structural formula for the major organic product in the following:
(1) LIAIH, ether
2 + LIOH + Al(OH)3
HO,
(2) H20
![Give the IUPAC names of the two reagents that would react in a Fischer esterification reaction to produce the ester shown.
(CH),CCOCH,
reagent 1-
reagent 2
Draw structural formulas for the anhydride and the amine (or ammonia) that react to form the amide shown.
CH, O
CH,CHCHČNHCH,CH,
You do not have to consider stereochemistry.
Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
Separate multiple reactants using the + sign from the drop-down menu.
Draw a structural formula for the missing organic product in the reaction below.
NH,
(CH)Cčočc(CH),
(CHCCOH
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• Do not include lone pairs in your answer. They will not be considered in the grading](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6cd0ba54-9c2f-4092-9f6d-bd36e9a12b87%2Fac0080ca-5229-4548-88a3-db49ceeb3075%2Fm0b33j_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Give the IUPAC names of the two reagents that would react in a Fischer esterification reaction to produce the ester shown.
(CH),CCOCH,
reagent 1-
reagent 2
Draw structural formulas for the anhydride and the amine (or ammonia) that react to form the amide shown.
CH, O
CH,CHCHČNHCH,CH,
You do not have to consider stereochemistry.
Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
Separate multiple reactants using the + sign from the drop-down menu.
Draw a structural formula for the missing organic product in the reaction below.
NH,
(CH)Cčočc(CH),
(CHCCOH
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• Do not include lone pairs in your answer. They will not be considered in the grading
Expert Solution
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Step 1
Note: Since you have asked multiple questions, we will solve the first question for you. If you want any specific question to be solved, then please specify the question number or post only that question.
LiAlH4 is a very powerful type of reducing agent as it can reduce most number of functional groups.
The hydride ion of this reagent is highly nucleophilic. The reason that this reagent is used in ether is because in water it reacts very violently.
However, If any carboxylic acid reacts with alcohol then it will result in the production of an ester.
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