Draw 3 additional resonance structures that demonstrate which atoms have partial positive character. CEN:

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**Exercise: Resonance Structures and IR Frequencies**

1. **Resonance Structures**
   - Draw 3 additional resonance structures that demonstrate which atoms have partial positive character.

   - Structure provided: A benzene ring attached to a carbon triple-bonded to a nitrogen (isocyanide).

2. **Infrared Frequencies**
   - The NH bonds in ammonia have an IR frequency of 3335 cm⁻¹, while the PH bonds in phosphine have an IR frequency of 2327 cm⁻¹. In a single sentence, describe the reason for the difference.

**Explanation:**

- **Diagram Description**: The initial structure shown illustrates a benzene ring connected to a C≡N group. This setup requires additional resonance structures to highlight partial positive charges on different atoms.

- **Reason for IR Frequency Differences**: The difference in IR frequencies is due to the stronger N-H bond in ammonia compared to the P-H bond in phosphine, resulting from nitrogen's higher electronegativity and bond strength.
Transcribed Image Text:**Exercise: Resonance Structures and IR Frequencies** 1. **Resonance Structures** - Draw 3 additional resonance structures that demonstrate which atoms have partial positive character. - Structure provided: A benzene ring attached to a carbon triple-bonded to a nitrogen (isocyanide). 2. **Infrared Frequencies** - The NH bonds in ammonia have an IR frequency of 3335 cm⁻¹, while the PH bonds in phosphine have an IR frequency of 2327 cm⁻¹. In a single sentence, describe the reason for the difference. **Explanation:** - **Diagram Description**: The initial structure shown illustrates a benzene ring connected to a C≡N group. This setup requires additional resonance structures to highlight partial positive charges on different atoms. - **Reason for IR Frequency Differences**: The difference in IR frequencies is due to the stronger N-H bond in ammonia compared to the P-H bond in phosphine, resulting from nitrogen's higher electronegativity and bond strength.
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