Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Exercise: Resonance Structures and IR Frequencies**
1. **Resonance Structures**
- Draw 3 additional resonance structures that demonstrate which atoms have partial positive character.
- Structure provided: A benzene ring attached to a carbon triple-bonded to a nitrogen (isocyanide).
2. **Infrared Frequencies**
- The NH bonds in ammonia have an IR frequency of 3335 cm⁻¹, while the PH bonds in phosphine have an IR frequency of 2327 cm⁻¹. In a single sentence, describe the reason for the difference.
**Explanation:**
- **Diagram Description**: The initial structure shown illustrates a benzene ring connected to a C≡N group. This setup requires additional resonance structures to highlight partial positive charges on different atoms.
- **Reason for IR Frequency Differences**: The difference in IR frequencies is due to the stronger N-H bond in ammonia compared to the P-H bond in phosphine, resulting from nitrogen's higher electronegativity and bond strength.
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