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Disulfides are compounds that have S— S bonds, like peroxideshave O— O bonds. Thiols are organic compoundsthat have the general formula R— SH, where R is a generichydrocarbon. The SH- ion is the sulfur counterpart ofhydroxide, OH-. Two thiols can react to make a disulfide,R— S— S— R. (a) What is the oxidation state of sulfur ina thiol? (b) What is the oxidation state of sulfur in a disulfide?(c) If you react two thiols to make a disulfide, are youoxidizing or reducing the thiols? (d) If you wanted to converta disulfide to two thiols, should you add a reducingagent or oxidizing agent to the solution? (e) Suggest whathappens to the H’s in the thiols when they form disulfides.

Disulfides are compounds that have S— S bonds, like peroxideshave O— O bonds. Thiols are organic compoundsthat have the general formula R— SH, where R is a generichydrocarbon. The SH- ion is the sulfur counterpart ofhydroxide, OH-. Two thiols can react to make a disulfide,R— S— S— R. (a) What is the oxidation state of sulfur ina thiol? (b) What is the oxidation state of sulfur in a disulfide?(c) If you react two thiols to make a disulfide, are youoxidizing or reducing the thiols? (d) If you wanted to converta disulfide to two thiols, should you add a reducingagent or oxidizing agent to the solution? (e) Suggest whathappens to the H’s in the thiols when they form disulfides.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Disulfides are compounds that have S— S bonds, like peroxides
have O— O bonds. Thiols are organic compounds
that have the general formula R— SH, where R is a generic
hydrocarbon. The SH- ion is the sulfur counterpart of
hydroxide, OH-. Two thiols can react to make a disulfide,
R— S— S— R. (a) What is the oxidation state of sulfur in
a thiol? (b) What is the oxidation state of sulfur in a disulfide?
(c) If you react two thiols to make a disulfide, are you
oxidizing or reducing the thiols? (d) If you wanted to convert
a disulfide to two thiols, should you add a reducing
agent or oxidizing agent to the solution? (e) Suggest what
happens to the H’s in the thiols when they form disulfides.

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