Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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discuss how determination of blood sugar level is done?

Transcribed Image Text:42 1-13 Disaccharides
CHEMICAL
CONNECTIONS 18
Changing Sugar Patterns: Decreased Sucrose, Increased Fructose
Prior to 1970, the natural sweetener added to prepared 1. Fructose (obtained from corn) is cheaper than sucrose
foods and beverages consumed by humans was almost
always the disaccharide sucrose (table sugar). Since that
time, sucrose use has steadily declined with the mono-
saccharide fructose progressively displacing sucrose as a
natural sweetener. Fructose use per capita per year is now
almost
Fructose, the most abúndant sugar in a variety of fruits
and some vegetables, has a "sweetness factor" that is 73%
greater than that of sucrose. (Chemical Connections 1-C
Sugar Substitutes-considers sweetness factors.) It is the alpha-amylase and glucoamylase (Section 4-3). The glu-
presence of fructose that gives ripe fruit its "extra" sweetness.
The role that fructose use plays in (1) the formulation isomerase to produce a mixture of glucose and fructose.
of fruit juice blends that are not 100% one juice and (2) the
formulation of prepared foods and other types of soft drink
beverages are considered in this Chemical Connection.
(1) The "base" juice for
always apple juice or
(obtained from sugar beets and sugar cane) in the
United States due to the relative abundance of corn,
farm subsidies for corn, and sugar import tarifs.
2. HFCS is easier to blend and transport because it is a liquid.
3. HFCS usage leads to products with a much longer shelf life.
equal to that of sucrose.
HFCS production involves milling corn to produce
corn starch and then hydrolyzing the starch (a glucose
polymer, Section 1-16) to glucose using the enzymes
cose so produced is then treated with the enzyme glucose
This latter enzymatic process produces a mixture whose
composition is 42% fructose, 50% glucose, and 8% other
sugars (HFCS-42). Concentration procedures are then
fruit juice blend is almost used to produce a syrup that is 90% fructose (HFCS-90).
HFCS-55, which is 55% fructose, 41% glucose, and 4%
other sugars, HFCS-55 is the sweetener of preference in
the soft drink industry. Its properties, including sweetness,
amount of a stronger flavored juice such as
blueberry or pomegranate juice. Why are apple juice and/
or pear juice the "base juice?" Apples and pears are the two
fruits with the highest fructose/glucose ratio and therefore are very similar to those of sucrose, which is 50% fructose
the greatest sweetness. The fructose/glucose ratio is almost and 50% glucose. HFCS-42 is commonly used as a sweet-
two times higher for these fruits than for most other fruits,
as shown
Note from this graphical information that some fruits also
contain significant amounts of sucrose itself, which when
hydrolyzed produces a 1-to-l mixture of fructose and glucose.
(2) Fructose is also used as a replacement for sucrose in question. Metabolic studies involving the two substances
many prepared foods and beverages other than fruit juice show almost identical results for sucrose and HFCS. Such
blends. Here, however, fruits are not the source for the fruc- results should be expected as sucrose is 50% glucose and
tose used. Rather, fructose in the form of high fructose corn
syrup (HFCS), made from milled corn, is the fructose source.
The replacement of sucrose with HFCS is mainly an sity problem probably relate to the fact that people who
economically driven decision. It costs less to sweeten prod- consume many sugary drinks have a higher caloric energy
ucts with HFCS than with sucrose for three reasons.
ener in many processed foods, and HFCS-90 is often used
in baked goods.
It is claimed by some health advocates that HFCS is
more harmful to consumers than sucrose. Current research
the following graphical information.
in
has not yet been able to give a definitive answer to this
50% fructose and HFCS has a ratio close to 1 for the two
sugars. Claims that HFCS products contribute to an obe-
intake than those who do not use such drinks daily.
Fructose/Glucose
Ratio**
Glucose
per Serving
Grapes 13.01g 53%
Pear 10.34 g 64%
9.61 g 55%
8,14 g 57%
7.21 g 50%
6.28 g
46%
1.1
2.1
Watermelon
26%
1.8
Apple
23%
2.0
Blueberries
Cherries
1.0
44%
0.82
Вanana
5.72 g
40%
0.98
Strawberries
4.15 g 54%
1.2
Pineapple
3.18 g
61
23%
1.1
26%
Orange
Raspberries
3.15 g
2,89 g
13
Peach
1.50 g
18%
24%
58%
0.92
Cantaloupe
1.29 g
24%
1.1
%Fructose %Glucose %Sucrose
* Serving size: 1 medium-sized fruit (apple, banana, orange, peach, pear); 1 cup (blueberries, cherries,
grapes, pineapple, raspberries, strawberries); 1/8 melon (cantaloupe); 1/16.melon (watermelon)
** Fructose/glucose ratio: Calculated treating the sucrose present as one-half fructose and one-half glucose.
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