Dicarboxylic acids have two pKa's. For maleic acid (cis-2-butenedioic acid) these are pka¹ = 2.0, and pKå² = 6.3 For fumaric acid (trans-2-butenedioic acid) these are pK₂¹ = 3.0, and pk₂² = 4.5 Which factor best explains why the cis-isomer has a smaller pK₂¹ and a larger pK₂² than the trans-isomer? 2 a. Intramolecular dipole repulsion b. Intramolecular steric hindrance c. Selective solvation in water O d. Intramolecular hydrogen bonding

Dicarboxylic acids have two pKa's. For maleic acid (cis-2-butenedioic acid) these are pka¹ = 2.0, and pKå² = 6.3 For fumaric acid (trans-2-butenedioic acid) these are pK₂¹ = 3.0, and pk₂² = 4.5 Which factor best explains why the cis-isomer has a smaller pK₂¹ and a larger pK₂² than the trans-isomer? 2 a. Intramolecular dipole repulsion b. Intramolecular steric hindrance c. Selective solvation in water O d. Intramolecular hydrogen bonding

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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