Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
For the reaction
Solve this using the data in the table below. For the reaction
Determine the reaction order with respect to each of the reactants. Hint: the reaction is 3rd order overall.
Determine k using the data from trial 1.
Write the rate law.
Using the rate law you just wrote, calculate the reaction rate if
the initial [ A ] = 0.046 M, the initial [ B ] = 0.10 M, and the initial [ C ] = 0.20 M. Enter the rate as a decimal number (no scientific notation, no units) with 2 significant figures.
The following data were obtained at constant temperature:
Trial | Initial (M) | Initial (M) | Initial (M) | Initial rate (M/s) |
1 | 0.0500 | 0.0500 | 0.0100 | 6.25 x 10^-3 |
2 | 0.1000 | 0.0500 | 0.0100 | 1.25 x 10^-2 |
3 | 0.1000 | 0.1000 | 0.0100 | 5.00 x 10^-2 |
4 | 0.0500 | 0.0500 | 0.0200 | 6.25 x 10^-3 |
Given:
Trial | Initial (M) | Initial (M) | Initial (M) | Initial rate (M/s) |
1 | 0.0500 | 0.0500 | 0.0100 | |
2 | 0.1000 | 0.0500 | 0.0100 | |
3 | 0.1000 | 0.1000 | 0.0100 | |
4 | 0.0500 | 0.0500 | 0.0200 |
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