Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Vibrational Modes of Trigonal Planar BF₃ Molecule**
**Description:**
Here we explore the four possible vibrational modes of a trigonal planar BF₃ molecule. Each mode is represented with arrows indicating the direction of motion. Arrows within the plane of the paper signify planar motion, while the + and – signs denote movements in and out of the plane.
**Mode 1:**
- The two fluorine atoms on the left and top move outwards, while the right-side fluorine moves downward, all within the plane of the paper.
**Mode 2:**
- Two of the fluorine atoms (left and right) move out of the plane (+), while the central boron and the bottom fluorine move into the plane (-).
**Mode 3:**
- The top fluorine atom moves outwards within the plane, while the central boron and bottom fluorine move vertically in alignment.
**Mode 4:**
- The left and right fluorine atoms move in opposite directions within the plane, while the top and bottom atoms, including boron, move vertically.
**Instructions:**
- Determine which of these modes should be IR-active and indicate your selection below.
- Options: Mode 1, Mode 2, Mode 3, Mode 4
This exercise aids in understanding vibrational spectroscopy and the infrared activity of different vibrational modes.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fce17c6ae-9240-4648-8795-951aa382f408%2F38ce537a-deea-47ae-80e1-7a74dc838326%2Fbbkmgnb_processed.png&w=3840&q=75)
Transcribed Image Text:**Vibrational Modes of Trigonal Planar BF₃ Molecule**
**Description:**
Here we explore the four possible vibrational modes of a trigonal planar BF₃ molecule. Each mode is represented with arrows indicating the direction of motion. Arrows within the plane of the paper signify planar motion, while the + and – signs denote movements in and out of the plane.
**Mode 1:**
- The two fluorine atoms on the left and top move outwards, while the right-side fluorine moves downward, all within the plane of the paper.
**Mode 2:**
- Two of the fluorine atoms (left and right) move out of the plane (+), while the central boron and the bottom fluorine move into the plane (-).
**Mode 3:**
- The top fluorine atom moves outwards within the plane, while the central boron and bottom fluorine move vertically in alignment.
**Mode 4:**
- The left and right fluorine atoms move in opposite directions within the plane, while the top and bottom atoms, including boron, move vertically.
**Instructions:**
- Determine which of these modes should be IR-active and indicate your selection below.
- Options: Mode 1, Mode 2, Mode 3, Mode 4
This exercise aids in understanding vibrational spectroscopy and the infrared activity of different vibrational modes.
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