Determine the proper stereochemistry (i.e., cis-, trans -, fac-, mer-, \Delta -, or \Lambda -) for the following complexes C Co CI CI CI H3N,, ...NH3 Co H3N CI NH3

Q: The geometry of a lanthanide complex is determined by steric hindrance arising from the ligands. * O…

A: Answer - True  According to the question - Given - The coordination number and geometry of the…

Q: Question 3 For the following coordination complex (Co(em)2(11,0)2)" Cive the name Diaqua bisethylene…

A:

Q: Show all electronic transition in the spectrum of a d3 complex. Scetch the appropriate spectrum.

A:

Q: Three peaks are observed at 9000, 14500, 24500 cm-1 in the [Ni(H2O)6]2+ uv-vis spectrum. What is the…

A:

Q: R) Tme Te acti different c why this is 1) Discuss We understanc

A: Coordination compounds are addition compounds which are formed when two or more salts are…

Q: For this species below, state the point group НО HO. For this species below, state the point group…

A: In chelation hard centre prefers hard donor centre. Here Sulphur is soft donor , N is less harder…

Q: 5) Consider the rhodium complex below. Reaction with 1 equivalent of oxygen gas oxidizes the metal…

A: Coordination complexes undergo different type of reactions which are oxidative addition reaction,…

Q: The factor determining the mechanism observed in the substitution reactions of square plane…

A: Substitution reactions in coordination complexes are the reactions in which one ligand in a complex…

Q: Below are the resonance structures of the sigma complex that is formed when the para position of…

A: The objective is to determine the instability in the resonance structure of sigma complex that is…

Q: НО. OH CF3 Br Br Bpin Ac₂O, pyr, DMAP COOH N3-1-O cal Fe(OAc)2/ligand CN BnNH₂ Pd₂(dba)3 SPhos K3PO4…

A:

Q: Which of the following statements about 10Dq is false? A. [VCl6]2- has a greater 10Dq than [VCl4]…

A: 10Dq is the splitting energy .  As there is strong field ligans sorroundinh the central atom , then…

Q: Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition?…

A: Spin selection rule: During the transition of electrons spin multiplicity should not change (ΔS =…

Q: Which option indicates, in order, whether the following compounds obey the effective atomic number…

A: EAN for K2[HgI4] is determined as shown below. Therefore, K2[HgI4] obeys the effective atomic number…

Q: Ph. Ph CI Me Pipr2 pipr2 PPH3 Co X.. Ph2 Ph2 PPH3 X = Cl Can someone help me find 1) the formal…

A: Oxidation state: For a metal Oxidation state is defined as degree of oxidation of metal. It is an…

Q: The -C=C-shown in the following complex, can be described as:

A: A ligand is an electron-rich species that donates the electron density by donating lone pair or…

Q: (a) Give the IUPAC name for the following complexes: (i) OEC Fe OC co Tc. OC (ii) CH3 (iv) CH3 H3C…

A: For naming of coordination compound, first name of ligands are written alphabetically and then name…

Q: 4) Rank the following sigma complexes in order of increasing stability. NO₂ A + H H3CO. Br B H -Br H…

A: Answer of this question :-  Sigma complex :- Sigma complex refers to an arenium ion. The suffix…

Q: 1. Arrange the following in order of increasing molar absorptivity &, and explain your ordering. a.…

A: Metal complexes are produced by the combination of the ligands with the unshared electron pairs. The…

Q: Determine the number of stereoisomers for square-planar metal complex: [PtCl2(en)]? en…

A:

Q: 3. Which complex shows lower C-O stretching frequency, [Ni(acac)2(H2O2 or [Ni(acac)2]? Explain.

A:

Q: The ppy ligand bears with inert complex. * substituent is expected to form the most CO2ME BF2 OH

A: For a ion/molecule to be inert in nature,  we discuss the 3 main factors which are: Smaller size…

Q: 5) Rank the following sigma complexes in order of increasing stability. H **$$ Br Br H NO₂ + A H Br…

A: Given:

Q: OEC Fe OC CO OC OEC (ii) CH3 (iv) CH3 H3C. CH3 CH3 As (OC):Os- OEU-

A: A complex is a substance wherein a metal ion or particle is related with a gathering of impartial…

Q: Q 2. Comment on the Kinetic and thermodynamic stability of metal complexes? (2 marks) (a) Which…

A: The objective of the question is to understand the kinetic and thermodynamic stability of metal…

Q: 5. Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.). H H₂N НО. OH…

A:

Q: the hexaquanickel(II) has a delta oct of 8,500cm-1. Calculate the CFSE of this complex with your…

A: CFSE = -10,200 cm-1

Q: multidentate ligands impreferable for complexometric titrations (А тоже. false doe B

A: multidentate ligand are preferable for complexometric titration

Q: IV. What do you observe from these structures. NG OH HO CN H.

A: As per the policy, we are only allowed to answer only 1st question. To get the answer of other…

Q: The type of the bonds drawn in red color is... H3 .C, RA R R Select one: a. 2e's-3c bond b. 1e's-2c…

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: 4. The following compound has 2 chirality centers. Identify each chiral centre and I dentify correct…

A: Chiral centre is an sp3 hybridised carbon having 4 different groups.

Q: Which of the following ligands will increase the value of A,? CN', CO, CI", N3-, en O Ct, N3- CO…

A: The Crystal Field Splitting (Δo) depends upon the nature of the ligands. The ligands which cause…

Q: 5. Do you think the 18-electron rule would hold better for a complex with ligands of strong pi-base…

A: The 18-electron rule is developed based on the electrons present in the valence orbitals of the…