Determine the pH of a Tris/TrisH* buffer solution by constructing an ICE table, writing the equilibrium constant expression, and using this information to determine the pH. The pKa for TrisH* is 8.30. Complete Parts 1-3 before submitting your answer. 1 Tris buffers are solutions of tris (hydroxymethyl)aminomethane, a weak base of formula C₂H₁NO3, combined with its protonated form, TrisH+, HC4H₁₁NO3*. A buffer solution is prepared by mixing 50.00 mL of 0.250 M Tris solution with 50.00 mL of 0.200 M TrisH solution. Fill in the ICE table with the appropriate value for each involved species to determine concentrations of all reactants and products. Initial (M) Change (M) Equilibrium (M) 0 2 HC4HNO3+ H₂O(1) H₂O*(aq) C4H₁NO3(ac 0.0125 +X 0.250 0.0125 - x 0.0125 + x 0.0100 - x 0.0100 + x 0.0100 - 2x Tap here or pull up for additional resources 0.0100 3 0.0125 - 2x RESET 0.200 -X 0.0125 + 2x 0.0100 + 2x
Determine the pH of a Tris/TrisH* buffer solution by constructing an ICE table, writing the equilibrium constant expression, and using this information to determine the pH. The pKa for TrisH* is 8.30. Complete Parts 1-3 before submitting your answer. 1 Tris buffers are solutions of tris (hydroxymethyl)aminomethane, a weak base of formula C₂H₁NO3, combined with its protonated form, TrisH+, HC4H₁₁NO3*. A buffer solution is prepared by mixing 50.00 mL of 0.250 M Tris solution with 50.00 mL of 0.200 M TrisH solution. Fill in the ICE table with the appropriate value for each involved species to determine concentrations of all reactants and products. Initial (M) Change (M) Equilibrium (M) 0 2 HC4HNO3+ H₂O(1) H₂O*(aq) C4H₁NO3(ac 0.0125 +X 0.250 0.0125 - x 0.0125 + x 0.0100 - x 0.0100 + x 0.0100 - 2x Tap here or pull up for additional resources 0.0100 3 0.0125 - 2x RESET 0.200 -X 0.0125 + 2x 0.0100 + 2x
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:10:47
Determine the pH of a Tris/TrisH* buffer solution
by constructing an ICE table, writing the
equilibrium constant expression, and using this
information to determine the pH. The pka for
TrisH* is 8.30. Complete Parts 1-3 before
submitting your answer.
Initial (M)
Change (M)
Question 4 of 13
Equilibrium (M)
1
Tris buffers are solutions of
tris (hydroxymethyl)aminomethane, a weak base
of formula C4H₁1NO3, combined with its
protonated form, TrisH*, HC₂H₁NO3*. A buffer
solution is prepared by mixing 50.00 mL of
0.250 M Tris solution with 50.00 mL of 0.200 M
TrisH+ solution. Fill in the ICE table with the
appropriate value for each involved species to
determine concentrations of all reactants and
products.
0.250
2
0
0.0125
HC4H₁NO3+H₂O(l) = H₂O*(aq) H₁NO3(ac
+X
0.0100
Submit
3
0.0125 - x
0.0125 + x
0.0100 - x
0.0100 + x
0.0100 - 2x
Tap here or pull up for additional resources
0.0125 - 2x
RESET
0.200
-X
0.0125 + 2x
0.0100 + 2x
![Determine the pH of a Tris/TrisH* buffer solution
by constructing an ICE table, writing the
equilibrium constant expression, and using this
information to determine the pH. The pka for
TrisH* is 8.30. Complete Parts 1-3 before
submitting your answer.
1
3
Based on your ICE table (Part 1) and the
definition of pKa, set up the expression for Ka in
order to determine the unknown. Each reaction
participant must be represented by one tile. Do
not combine terms.
K₂ =
[0.200]
[0.200 -x]
[0.0125 - 2x]
[0.0100 - 2x]
-8.30
[0.250]
[0.250 + x]
[0.0125 + 2x]
[0.0100 + 2x]
5.01x 10-⁹
[0.0125]
[0.0125 -x]
[0.0100 -x]
9.12 x 10-²
[x]
Tap here or pull up for additional resources
0
>
RESET
[0.0100]
[0.0125 + x]
[0.0100 + x]
8.30
[-x]
7.61
estion 4 of 13
Determine the pH of a Tris/TrisH* buffer solution
by constructing an ICE table, writing the
equilibrium constant expression, and using this
information to determine the pH. The pka for
TrisH* is 8.30. Complete Parts 1-3 before
submitting your answer.
1
2
3
Based on your ICE table (Part 1) and the
equilibrium expression for Ka (Part 2),
determine the pH of the buffer solution.
pH =
5.01 x 10-⁹
5.60
Submit
0.200
0.26
RESET
8.40](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F41d4ecd7-dcd4-443e-8d95-d66e36528238%2F49b59bbc-5ee9-415a-bd57-07a1e4d7e1e9%2Fv3t0pob_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Determine the pH of a Tris/TrisH* buffer solution
by constructing an ICE table, writing the
equilibrium constant expression, and using this
information to determine the pH. The pka for
TrisH* is 8.30. Complete Parts 1-3 before
submitting your answer.
1
3
Based on your ICE table (Part 1) and the
definition of pKa, set up the expression for Ka in
order to determine the unknown. Each reaction
participant must be represented by one tile. Do
not combine terms.
K₂ =
[0.200]
[0.200 -x]
[0.0125 - 2x]
[0.0100 - 2x]
-8.30
[0.250]
[0.250 + x]
[0.0125 + 2x]
[0.0100 + 2x]
5.01x 10-⁹
[0.0125]
[0.0125 -x]
[0.0100 -x]
9.12 x 10-²
[x]
Tap here or pull up for additional resources
0
>
RESET
[0.0100]
[0.0125 + x]
[0.0100 + x]
8.30
[-x]
7.61
estion 4 of 13
Determine the pH of a Tris/TrisH* buffer solution
by constructing an ICE table, writing the
equilibrium constant expression, and using this
information to determine the pH. The pka for
TrisH* is 8.30. Complete Parts 1-3 before
submitting your answer.
1
2
3
Based on your ICE table (Part 1) and the
equilibrium expression for Ka (Part 2),
determine the pH of the buffer solution.
pH =
5.01 x 10-⁹
5.60
Submit
0.200
0.26
RESET
8.40
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