Determine the pH during the titration of 37.3 mL of 0.336 M methylamine (CH3NH2, K = 4.2×10*) by 0.336 M HI at the following points. (Assume the titration is done at 25 °C.) Note that state symbols are not shown for species in this problem. (a) Before the addition of any HI (b) After the addition of 16.2 mL of HI (c) At the titration midpoint

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Chapter1: Chemical Foundations
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**Titration of Weak Base with Strong Acid**

The reaction of a weak base and a strong acid reaches completion as one of the reactants is entirely used up. The resulting solution will contain the conjugate acid of the weak base, with any remaining weak base or strong acid left unreacted.

**At Each Stage of the Titration:**

A. Calculate the moles of weak acid, weak base, and strong acid present.
B. Determine the total volume of the mixed solutions.
C. Establish whether \([H_3O^+]\) or \([OH^-]\) predominates, considering the solution's total volume and its nature (weak base, buffer, weak acid, strong acid).
D. Calculate the pH.

**Titration Problem:**

Calculate the pH during the titration of 37.3 mL of 0.336 M methylamine (\(CH_3NH_2\), \(K_b = 4.2 \times 10^{-4}\)) with 0.336 M HI at the following stages (assume a temperature of 25°C):

- **(a) Before the addition of any HI**: [pH calculation required]
- **(b) After the addition of 16.2 mL of HI**: [pH calculation required]
- **(c) At the titration midpoint**: [pH calculation required]
- **(d) At the equivalence point**: [pH calculation required]
- **(e) After adding 56.0 mL of HI**: [pH calculation required]

Note: State symbols for species in this problem are omitted.
Transcribed Image Text:**Titration of Weak Base with Strong Acid** The reaction of a weak base and a strong acid reaches completion as one of the reactants is entirely used up. The resulting solution will contain the conjugate acid of the weak base, with any remaining weak base or strong acid left unreacted. **At Each Stage of the Titration:** A. Calculate the moles of weak acid, weak base, and strong acid present. B. Determine the total volume of the mixed solutions. C. Establish whether \([H_3O^+]\) or \([OH^-]\) predominates, considering the solution's total volume and its nature (weak base, buffer, weak acid, strong acid). D. Calculate the pH. **Titration Problem:** Calculate the pH during the titration of 37.3 mL of 0.336 M methylamine (\(CH_3NH_2\), \(K_b = 4.2 \times 10^{-4}\)) with 0.336 M HI at the following stages (assume a temperature of 25°C): - **(a) Before the addition of any HI**: [pH calculation required] - **(b) After the addition of 16.2 mL of HI**: [pH calculation required] - **(c) At the titration midpoint**: [pH calculation required] - **(d) At the equivalence point**: [pH calculation required] - **(e) After adding 56.0 mL of HI**: [pH calculation required] Note: State symbols for species in this problem are omitted.
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