Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Determining the Major Product(s) of the Reaction
**Reaction Given:**
- **Reactants:**
- Benzene ring (C₆H₅)
- 2-chloropropane (CH₃CHClCH₃)
- **Catalyst:**
- Aluminum chloride (AlCl₃)
**Objective:**
Determine the major product(s) of the reaction when benzene reacts with 2-chloropropane in the presence of AlCl₃.
**Possible Major Products:**
There are four possible product structures shown:
1. **Structure 1:**
- Benzene ring attached to a propyl group (C₆H₅-CH₂CH₂CH₃)
2. **Structure 2:**
- Benzene ring attached to a secondary butyl group, with a chlorine atom on the adjacent carbon (C₆H₅-CHClCH₂-CH₃)
3. **Structure 3:**
- Benzene ring attached to a secondary butyl group (C₆H₅-CH₂CH₂CH₃)
4. **Structure 4:**
- Benzene ring attached to a propyl group (C₆H₅-CH₂CH₂CH₃)
Please revise the numbering based on the actual product structures you encounter.
**Explanation:**
1. **Benzene to Propyl Group (Structure 1):**
- This structure shows the benzene ring directly attached to the carbon chain that forms a propyl group.
2. **Benzene to Secondary Butyl with Chlorine (Structure 2):**
- This structure indicates that the benzene ring has attached to the carbon chain forming a secondary butyl group and additionally has a chlorine atom on one of the adjacent carbons.
3. **Benzene to Secondary Butyl Group(Structure 3):**
- This option illustrates the benzene ring attached to a secondary butyl group, lacking the chlorine atom from the second structure.
**Outcome:**
Select the structure that accurately represents the major product of the reaction as per the Fischer projection and resonance stabilization.
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