Determine the  ΔH for the reaction below using Bond Energies.                                   CH4(g)     +    2O2(g)  →  CO2(g)    +  2H2O(l)

Chemistry for Engineering Students
3rd Edition
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter9: Energy And Chemistry
Section: Chapter Questions
Problem 9.61PAE: When a reaction is exothermic, is the sum of bond energies of products or of reactants greater?
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  1.  Determine the  ΔH for the reaction below using Bond Energies. 

                                 CH4(g)     +    2O2(g)  →  CO2(g)    +  2H2O(l)

 

Average Bond Energies (kJ/mol)
Single Bonds
H-H
432
H-F
565
H-CI 427
H-Br 363
H-I
295
C-H
413
C-C
347
C-N
305
C-O
358
C-F
485
C-CI 339
C-Br 276
C-I
240
C-S
259
N-H
N-N
N-F
N-CI
N-Br
N-O
O-H
0-0
O-F
O-CI
0-I
391
I-I
160 I-CI
272
I-Br
200
243
S-H
201 S-F
467
S-CI
146
S-Br
190
S-S
203
234
F-F
154
F-CI
253
F-Br
237
CI-CI
239
Cl-Br 218
Br-Br
193
Si-Si
Si-H
Si-C
Si-O
149
208
175
347
327
253
218
266
340
393
360
452
Multiple Bonds
C=C
614
C=C
839
0=0
495
C=0*
745
1072
607
418
N=O
N=N
N=N
C=N
C=N
941
891
615
*C=O(CO₂) = 799
Transcribed Image Text:Average Bond Energies (kJ/mol) Single Bonds H-H 432 H-F 565 H-CI 427 H-Br 363 H-I 295 C-H 413 C-C 347 C-N 305 C-O 358 C-F 485 C-CI 339 C-Br 276 C-I 240 C-S 259 N-H N-N N-F N-CI N-Br N-O O-H 0-0 O-F O-CI 0-I 391 I-I 160 I-CI 272 I-Br 200 243 S-H 201 S-F 467 S-CI 146 S-Br 190 S-S 203 234 F-F 154 F-CI 253 F-Br 237 CI-CI 239 Cl-Br 218 Br-Br 193 Si-Si Si-H Si-C Si-O 149 208 175 347 327 253 218 266 340 393 360 452 Multiple Bonds C=C 614 C=C 839 0=0 495 C=0* 745 1072 607 418 N=O N=N N=N C=N C=N 941 891 615 *C=O(CO₂) = 799
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