Determine enthalpy of vaporization graphically using the Clausius-Clapeyron equation. The vapor pressure of iodomethane (CH3I) has been measured over a range of temperatures. (a) Which of the following should give a linear plot (temperatures in K)? On the x-axis: On the y-axis: (b) When the appropriate plot is made, the resulting straight line has a slope of -3.65x10° K. Use this information to determine AHvap for CH3I. kJ/mol
States of Matter
The substance that constitutes everything in the universe is known as matter. Matter comprises atoms which in turn are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction, namely solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).
Chemical Reactions and Equations
When a chemical species is transformed into another chemical species it is said to have undergone a chemical reaction. It consists of breaking existing bonds and forming new bonds by changing the position of electrons. These reactions are best explained using a chemical equation.
![Determine enthalpy of vaporization graphically using the Clausius-Clapeyron equation.
The
vapor pressure of iodomethane (CH3I) has been measured over a range of temperatures.
(a) Which of the following should give a linear plot (temperatures in K)?
On the x-axis:
On the y-axis:
(b) When the appropriate plot is made, the resulting straight line has a slope of -3.65x10° K.
Use this information to determine AHvap
for CH3I.
kJ/mol
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Example Problem 11.2.5
Use the two-point version of the Clausius-Clapeyron equation
The vapor pressure of liquid aluminum is 400. mm Hg at 2590 K. Assuming that AHvap for Al (29
change significantlv with temperature.calculate the vapor pressure of liauid Al at 2560 K.
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