Determination of Electrochemical Cell Characteristics One-half of an electrochemical cell consists of a pure nickel electrode in a solution of Ni** ions; the other half is a cadmium electrode immersed in a Cd²* solution. (a) If the cell is a standard one, write the spontaneous overall reaction and calculate the voltage that is generated. (b) Compute the cell potential at 25°C if the Cd² and Ni2* concentrations are 0.5 and 10M, respectively. Is the spontaneous reaction direction still the same as for the standard cell? Cd +2e → Cd E =-0.403V %3D Ni +2e Ni E=-0.250V %3D

Introduction to Chemical Engineering Thermodynamics
8th Edition
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Determination of Electrochemical Cell Characteristics
One-half of an electrochemical cell consists ofa pure nickel electrode in a solution
of Ni** ions; the other half is a cadmium electrode immersed in a Cd² solution.
(a) If the cell is a standard one, write the spontaneous overall reaction and
calculate the voltage that is generated.
(b) Compute the cell potential at 25°C if the Cd² and Ni2 concentrations
are 0.5 and 10 M, respectively. Is the spontaneous reaction direction still the
same as for the standard cell?
Cd +2e Cd
E=-0.403V
E =-0.250V
Ni +2e Ni
Transcribed Image Text:Example: Determination of Electrochemical Cell Characteristics One-half of an electrochemical cell consists ofa pure nickel electrode in a solution of Ni** ions; the other half is a cadmium electrode immersed in a Cd² solution. (a) If the cell is a standard one, write the spontaneous overall reaction and calculate the voltage that is generated. (b) Compute the cell potential at 25°C if the Cd² and Ni2 concentrations are 0.5 and 10 M, respectively. Is the spontaneous reaction direction still the same as for the standard cell? Cd +2e Cd E=-0.403V E =-0.250V Ni +2e Ni
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