Design a buffer that has a pH of 7.76 using one of the weak acid/conjugate base systems shown below. Weak Acid Conjugate Base Ka pka HC₂04 C₂04²- 6.4 x 10-5 4.19 H₂PO4 HPO4²- 6.2 x 10-8 7.21 HCO3 CO3²- 4.8 x 10-11 10.32 How many grams of the potassium salt of the weak acid must be combined with how many grams of the potassium salt of its conjugate base, to produce 1.00 L of a buffer that is 1.00 M in the weak base? grams potassium salt of weak acid = grams potassium salt of conjugate base =

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Designing a Buffer Solution**

To design a buffer with a pH of 7.76 using one of the weak acid/conjugate base systems shown below, consider the following data:

| Weak Acid | Conjugate Base | \( K_a \) | \( pK_a \) |
|-----------|----------------|-----------|-----------|
| \( \text{HC}_2\text{O}_4^- \) | \( \text{C}_2\text{O}_4^{2-} \) | \( 6.4 \times 10^{-5} \) | \( 4.19 \) |
| \( \text{H}_2\text{PO}_4^- \) | \( \text{HPO}_4^{2-} \) | \( 6.2 \times 10^{-8} \) | \( 7.21 \) |
| \( \text{HCO}_3^- \) | \( \text{CO}_3^{2-} \) | \( 4.8 \times 10^{-11} \) | \( 10.32 \) |

**Problem Statement:**
Calculate how many grams of the potassium salt of the weak acid must be combined with how many grams of the potassium salt of its conjugate base, to produce 1.00 L of a buffer that is 1.00 M in the weak base.

**Buffer Preparation:**
- **Grams of potassium salt of weak acid:** 
  - \[ \text{Enter value} \]

- **Grams of potassium salt of conjugate base:** 
  - \[ \text{Enter value} \]

To solve this problem, you need to:

1. **Select the appropriate acid/base pair:** Choose the weak acid and its conjugate base that has a \( pK_a \) value close to your target pH for the buffer.

2. **Use the Henderson-Hasselbalch equation:** This equation relates the pH of the buffer to the \( pK_a \) and the concentrations of the acid and its conjugate base.
   \[ \text{pH} = pK_a + \log\left( \frac{[\text{base}]}{[\text{acid}]} \right) \]

3. **Determine the ratio of the conjugate base to the acid:** Using the desired pH and the chosen
Transcribed Image Text:**Designing a Buffer Solution** To design a buffer with a pH of 7.76 using one of the weak acid/conjugate base systems shown below, consider the following data: | Weak Acid | Conjugate Base | \( K_a \) | \( pK_a \) | |-----------|----------------|-----------|-----------| | \( \text{HC}_2\text{O}_4^- \) | \( \text{C}_2\text{O}_4^{2-} \) | \( 6.4 \times 10^{-5} \) | \( 4.19 \) | | \( \text{H}_2\text{PO}_4^- \) | \( \text{HPO}_4^{2-} \) | \( 6.2 \times 10^{-8} \) | \( 7.21 \) | | \( \text{HCO}_3^- \) | \( \text{CO}_3^{2-} \) | \( 4.8 \times 10^{-11} \) | \( 10.32 \) | **Problem Statement:** Calculate how many grams of the potassium salt of the weak acid must be combined with how many grams of the potassium salt of its conjugate base, to produce 1.00 L of a buffer that is 1.00 M in the weak base. **Buffer Preparation:** - **Grams of potassium salt of weak acid:** - \[ \text{Enter value} \] - **Grams of potassium salt of conjugate base:** - \[ \text{Enter value} \] To solve this problem, you need to: 1. **Select the appropriate acid/base pair:** Choose the weak acid and its conjugate base that has a \( pK_a \) value close to your target pH for the buffer. 2. **Use the Henderson-Hasselbalch equation:** This equation relates the pH of the buffer to the \( pK_a \) and the concentrations of the acid and its conjugate base. \[ \text{pH} = pK_a + \log\left( \frac{[\text{base}]}{[\text{acid}]} \right) \] 3. **Determine the ratio of the conjugate base to the acid:** Using the desired pH and the chosen
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps with 3 images

Blurred answer
Knowledge Booster
Acid-Base Titrations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY