Describe how the bond angles in TeF4 and BrF5 deviate from those found in a trigonal bipyramidal and an octahedron, respectively. In TeF4, the lone pair of electrons repels the Te-F bonding pairs, causing the F-Te-F angles to be smaller than v in the ideal trigonal bipyramid. In BRF5, the lone pair is located perpendicular v to the plane of four of the F atoms, giving a square pyramid geometry to the molecule. The angle between the four F in the plane and the F above the plane will be less than v 90° due to lone pair repulsion. The F-Br-F angles in the plane will remain i
Describe how the bond angles in TeF4 and BrF5 deviate from those found in a trigonal bipyramidal and an octahedron, respectively. In TeF4, the lone pair of electrons repels the Te-F bonding pairs, causing the F-Te-F angles to be smaller than v in the ideal trigonal bipyramid. In BRF5, the lone pair is located perpendicular v to the plane of four of the F atoms, giving a square pyramid geometry to the molecule. The angle between the four F in the plane and the F above the plane will be less than v 90° due to lone pair repulsion. The F-Br-F angles in the plane will remain i
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter9: Covalent Bonding: Orbitals
Section: Chapter Questions
Problem 76AE: Complete the following resonance structures for POCl3. a. Would you predict the same molecular...
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