Describe how the bond angles in TeF4 and BrF5 deviate from those found in a trigonal bipyramidal and an octahedron, respectively. In TeF4, the lone pair of electrons repels the Te-F bonding pairs, causing the F-Te-F angles to be smaller than v in the ideal trigonal bipyramid. In BRF5, the lone pair is located perpendicular v to the plane of four of the F atoms, giving a square pyramid geometry to the molecule. The angle between the four F in the plane and the F above the plane will be less than v 90° due to lone pair repulsion. The F-Br-F angles in the plane will remain i

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Chapter9: Covalent Bonding: Orbitals
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Problem 76AE: Complete the following resonance structures for POCl3. a. Would you predict the same molecular...
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Describe how the bond angles in TeF4 and BRF5 deviate from those found in a trigonal bipyramidal and an octahedron,
respectively.
In TeF4, the lone pair of electrons repels the Te-F bonding pairs, causing the F-Te-F angles to be
smaller than
v in the ideal
trigonal bipyramid.
In BrF5, the lone pair is located
perpendicular v to the plane of four of the F atoms, giving a
square pyramid
v geometry to
the molecule. The angle between the four E in the plane and the F above the plane will be
less than
v 90° due to lone pair
repulsion. The F-Br-F angles in the plane will remain
DEC
étv
MacBook Air
DD
F4
F5
F6
F7
F8
F9
F10
F2
F3
@
#
2$
3
4
6.
8.
S LO
Transcribed Image Text:Describe how the bond angles in TeF4 and BRF5 deviate from those found in a trigonal bipyramidal and an octahedron, respectively. In TeF4, the lone pair of electrons repels the Te-F bonding pairs, causing the F-Te-F angles to be smaller than v in the ideal trigonal bipyramid. In BrF5, the lone pair is located perpendicular v to the plane of four of the F atoms, giving a square pyramid v geometry to the molecule. The angle between the four E in the plane and the F above the plane will be less than v 90° due to lone pair repulsion. The F-Br-F angles in the plane will remain DEC étv MacBook Air DD F4 F5 F6 F7 F8 F9 F10 F2 F3 @ # 2$ 3 4 6. 8. S LO
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