Derivation Starting with the relation P = -(JA/V)T, show that P = kBT(à In Q/V)T. Using argon as an example of an ideal monatomic gas, derive the ideal-gas equation (PV = nRT). Step 1 of 7 Give the equation for the Helmholtz energy, A. (Use the following as necessary: S, T, and U.) A = U-TS Give the equation for entropy that contains the canonical partition function, Q. (Use the following as necessary: E, kB, Q, and T.) 3 S = ³/R + kBQ X Submit
Derivation Starting with the relation P = -(JA/V)T, show that P = kBT(à In Q/V)T. Using argon as an example of an ideal monatomic gas, derive the ideal-gas equation (PV = nRT). Step 1 of 7 Give the equation for the Helmholtz energy, A. (Use the following as necessary: S, T, and U.) A = U-TS Give the equation for entropy that contains the canonical partition function, Q. (Use the following as necessary: E, kB, Q, and T.) 3 S = ³/R + kBQ X Submit
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Starting with the relation P = -(A/V), show that P = kÊT(à In Q/V). Using argon as an example of an ideal monatomic gas, derive the ideal-gas equation (PV = nRT).
Step 1 of 7
Give the equation for the Helmholtz energy, A. (Use the following as necessary: S, T, and U.)
A = U-TS
Give the equation for entropy that contains the canonical partition function, Q. (Use the following as necessary: E, kB, Q, and T.)
3
S =
³/₂R+kBQ
X
Submit"
Transcribed Image Text:Derivation
Starting with the relation P = -(A/V), show that P = kÊT(à In Q/V). Using argon as an example of an ideal monatomic gas, derive the ideal-gas equation (PV = nRT).
Step 1 of 7
Give the equation for the Helmholtz energy, A. (Use the following as necessary: S, T, and U.)
A = U-TS
Give the equation for entropy that contains the canonical partition function, Q. (Use the following as necessary: E, kB, Q, and T.)
3
S =
³/₂R+kBQ
X
Submit
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