Decomposition of N2O5 in CC14 at 45°C is known to follow a First-order kinetics. The specific rate constant for this decomposition process at the above temperature is 6.32 × 10¬* s. (a) If the initial concentration of N2O5 was 0.500 M, then what will be the concentration of N2O5 remaining (not decomposed) after 2.00 hr? (b) For 90% of the N2O5 to decompose, how much time will be required? (c) From the following decomposition data of N2O5, calculate the activation energy (Ea). T1 = 35°C, kị = 6.60 ×10-5 s=1 and T2 = 65°C, k2 = 2.40 ×10-3 s-1.

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Decomposition of N2O5 in CC14 at 45°C is known to follow a First-order kinetics. The specific rate
constant for this decomposition process at the above temperature is 6.32 × 10* s.
(a) If the initial concentration of N2O5 was 0.500 M, then what will be the concentration of
N2O5 remaining (not decomposed) after 2.00 hr?
(b) For 90% of the N2O5 to decompose, how much time will be required?
(c) From the following decomposition data of N2O5, calculate the activation energy (Ea).
Ti = 35°C, k = 6.60 ×10-5 s
and
T2 = 65°C, k2 = 2.40 ×10 ³ s1.
Transcribed Image Text:Decomposition of N2O5 in CC14 at 45°C is known to follow a First-order kinetics. The specific rate constant for this decomposition process at the above temperature is 6.32 × 10* s. (a) If the initial concentration of N2O5 was 0.500 M, then what will be the concentration of N2O5 remaining (not decomposed) after 2.00 hr? (b) For 90% of the N2O5 to decompose, how much time will be required? (c) From the following decomposition data of N2O5, calculate the activation energy (Ea). Ti = 35°C, k = 6.60 ×10-5 s and T2 = 65°C, k2 = 2.40 ×10 ³ s1.
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