Please follow the sample i provide. dd. cyclohexanone + 2 equivalents of ethanol1. React the carbonyl compound:It is (circle one) CONJUGATEDNON-CONJUGATEDThe Nucleophile isPotential to Establish a Resonance SystemOption 1: Almost all reactionsOption 2: When Nu is a strong base (OH or OR),1 Preferred)and the leaving group is identical to the Nu(option 1 is react the electron-rich nucleophilewith the electron- deficient carbonyl carbon)(option 2 is remove the alpha hydrogen andcreate a resonance-stabilized carbanion that canact as a nucleophile.)Circle the option and reason for reacting with aparticular site of the carbonyl compoundOption 1: Always use UNLESSOption 2: The Nu matches Y AND is -OR2. Take care of the negative formal charge of the oxygen in the tetrahedral complexOption 1 (Preferred): All cases except Option 21 (Preferred)Option 2: If there are no leaving groups,Ror if the only potential leaving group isthe Nu that was just added and itis not a very good leaving group (N or O).(option 1 is reform the double bond)(option 2 is add a hydrogen ion)Circle the option and reason* if you reform the Double bondWhots tleReason?Option 1: Always use UNLESS- LeGuing group?- Shells ?elec tranegativity?Option 2: There is no leaving group (there arecharge ?carbons and hydrogens), OR there are onlycarbons and hydrogens except for the Nu thatjust added, AND it is N or O.3. Check to see if the reaction continues(xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.) z. hex-4-en-3-one + CH3CH2MBBR1. React the carbonyl compound:It is (circle one) CONJUGATEDNON-CONJUGATEDCH3 - CH2The Nucleophile isCH, - CH - ĕ - CH = CH;-Clls- CH =CH;-CH3Resonance SystemOption 1: Only the Nu createdfrom RMgBr, NaBH , or LIAIH, sticksCH3-CH E- CH=cH-CH3R-CH CHFROption 2: All other Nu end up here eventually1 (Preferred)NUBCH3-CH,(option 1 is react the electron-rich nucleophilewith the electron- deficient carbonyl carbon)(option 2 is to react the electron-rich nucleophilewith the slightly electron-deficient carbon at theend of the resonance system.)Circle the option and reason for reacting with aparticular site of the carbonyl compoundOption 1: RMgBr, LIAIH4, or NaBH4Option 2: All other Nu end up sticking here2. Take care of the negative formal charge of the oxygen in the tetrahedral complexOption 1 (Preferred): All cases except Option 2:0:7HtCHe-(- CH -CH-CH3CH2-CH31 (Preferred)Option 2: If there are no leaving groups,R.or if the only potential leaving group isthe Nu that was just added and itis not a very good leaving group (N or O).(option 1 is reform the double bond)(option 2 is add a hydrogen ion)Circle the option and reasonOption 1: Always use UNLESS* ifyou reform theDOuble bondOption 2: There is no leaving group (there arecarbons and hydrogens), OR there are onlywhatstheReason?EWA/ ReASonae?carbons and hydrogens except for the Nu thatjust added, AND it is N or O.- Leauing group?- Shells ?- electronegativity?charge ?3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electronpairs.)

Solution : Nucleophiles are chemical species that have the capacity of donating an electron…

dd. cyclohexanone + 2 equivalents of ethanol 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED The Nucleophile is Potential to Establish a Resonance System Option 1: Almost all reactions Option 2: When Nu is a strong base (OH or OR), 1 (Preforred) and the leaving group is identical to the Nu (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is remove the alpha hydrogen and create a resonance-stabilized carbanion that can act as a nucleophile.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: Always use UNLESS Option 2: The Nu matches Y AND is -OR 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason reform the Double bond you the whats Reason? Option 1: Always use UNLESS EwA/ REASonae? ouing group? hells ? lec trinegativity? Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only - charge . carbons and hydrogens except for the Nu that just added, AND it is N or O. 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...