D. The wave-functions corresponding to the energy levels are shown below as linear combinations of atomic orbitals. For each indicate which energy level it corresponds to and label it as bonding, antibonding, or non-bonding. The symmetry species for the orbitals are 2A2+2B2. Label each orbital with the correct symmetry species. z & S &g 88 T C₁ (x²) xyz) G|--77 11.10 x. R. ..
D. The wave-functions corresponding to the energy levels are shown below as linear combinations of atomic orbitals. For each indicate which energy level it corresponds to and label it as bonding, antibonding, or non-bonding. The symmetry species for the orbitals are 2A2+2B2. Label each orbital with the correct symmetry species. z & S &g 88 T C₁ (x²) xyz) G|--77 11.10 x. R. ..
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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please solve question 4
Transcribed Image Text:3.
Consider the a bonding of the cis-1,3-butadiene molecule of C2v symmetry in the xz
plane with the carbon atoms numbered as indicated
CH2
A..
Using the Hückel method write the secular determinant that must be solved to
determine the energies of the x orbitals of this molecule. Write this in terms of a and B.
B.
Often a is set to zero and B is set to unity. In this case what would an energy
value of -1.62 correspond to relative to other energy values?
C.
The energy solutions for part A are 1.62B, 0.62B, -0.62B, and -1.62B. Draw an
energy diagram for these levels and show the location of the electrons. What is the a bond
stabilization for this molecule in B units?
D.
linear combinations of atomic orbitals. For each indicate which energy level it corresponds
to and label it as bonding, antibonding, or non-bonding. The symmetry species for the
orbitals are 2A2+ 2B2. Label each orbital with the correct symmetry species.
The wave-functions corresponding to the energy levels are shown below as
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