d. Kinetic barriers can stop a reaction even if there is a thermodynamic driving force for transformation. e. The rate of a reaction is more sensitive to temperature changes if the acti- vation energy is smaller. f. The rate of a reaction depends on the free energy change for the reaction.

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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d. Kinetic barriers can stop a reaction even if there is a thermodynamic driving
force for transformation.
e. The rate of a reaction is more sensitive to temperature changes if the acti-
vation energy is smaller.
f. The rate of a reaction depends on the free energy change for the reaction.
g. The "saddle point" is the highest point on a potential energy surface.
h. For a given activation energy, temperature changes have more effect on the
rate constant at lower temperatures.
i. A process is operating at a mean temperature; the temperature oscillating
with a fixed frequency for a given time; the extent of reaction is more if the
amplitude of temperature fluctuation is greater.
j.I A catalyst cannot change the driving force of a reaction.
k.. The rate constant of a reaction increases a hundredfold when the tempera-
ture rise is 200 °C. The rate constant will increasing more than fifty times if
the temperature rise is 100 °C.
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Transcribed Image Text:by Hem Shanker Ray, Saradindukumar Ray (z-lib.org).pdf - Adobe Reader (44 of 480)- + 13 187% Comment olies with the PDF/A standard and has been opened read-only to prevent modification. d. Kinetic barriers can stop a reaction even if there is a thermodynamic driving force for transformation. e. The rate of a reaction is more sensitive to temperature changes if the acti- vation energy is smaller. f. The rate of a reaction depends on the free energy change for the reaction. g. The "saddle point" is the highest point on a potential energy surface. h. For a given activation energy, temperature changes have more effect on the rate constant at lower temperatures. i. A process is operating at a mean temperature; the temperature oscillating with a fixed frequency for a given time; the extent of reaction is more if the amplitude of temperature fluctuation is greater. j.I A catalyst cannot change the driving force of a reaction. k.. The rate constant of a reaction increases a hundredfold when the tempera- ture rise is 200 °C. The rate constant will increasing more than fifty times if the temperature rise is 100 °C. Activate Wipdows Go to Settin 633 AM 下 O # O e a 7/19/2021 earch home end delete prt sc 144 144 backspace lock & 7 08.
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