d. For the IR spectrum for product B, identify which functional groups are suggested by the signals indicated by each of thearrows. (Be sure to include whether the signal is due to a stretching vibration or a banding vibration for this question.)mmmt.For the NMR spectrum for product B, draw the structure of the product next to the spectrum and label the proton so thatthey match the letter labels shown on the NMR spectrum. Fill in the Chemical shift, inkgosion, and multiplicity in the table.9SepteSTRUCTURE:Integration-1DoubletIntegration - 6ProtonlabelFHChemical R(ppm)Explain the multiplicity and relative integration for the peak labelled Ha.Explain the multiplicity and relative integration for the peak labelled Hr.RevintegrationMultiply a)M₂C.Step 4: c) 1H-NMR analysis of product ACDThe hydrolysis of an emide involves the cleavage of the amide bond, which is a carbonyl group (C=0)bonded to a nitrogen atom. This reaction is typically catalyzed by an acid or a base.EStep 3: b)IR analysis of product A:The broad peaks in the range of 3500 cm³ to 2500cm* indicate O-H stretching frequency of COOHfunctional group...The strong, narrow peak around 1720 cm* indicates C=0 stretching frequency of COOH.The medium, sharp peak around 1600cm* indicates C-C stretching frequency of benzene ringProton A: The small, broad peak around 12 ppm indicates O-H of COOH.Proton B and proton C: The doublets at 8.1ppm, 7.1ppm indicate di-substituted benzene.Proton D: The quartet at 2.4 ppm indicate CH₂ unit with adjacent CH₂ unit.Proton E: Triplet et 1.1 ppm indicate CH₂ unit with adjacent CH₂ unit.Proton labelrelative integrationA1B1123SolutionHH₂OHeat H₂G.1600 cmProduct Achemical shift12ppm8.1ppm7.1ppm24ppm1.1ppmH₂C.HOHa) Hydrolysis of amide yields an acid and amine.b) and c) The IR peak showing functional group and chemical shift values of proton for the given amide isshown below1720 cm18.1ppm, doublet. HNH₂Product B12ppm broad singlet, IH3500-2550 cm7.1ppm, doublet, IHmultiplicitybroad singletdoubletdoubletquartettriplet

Spectral analysis is an important method for determining the structure of an organic compound. IR…

d. For the spectrum for product, identify which functional groups are suggested by the signals indicated by each of the include whether the signal is d to a stretching vibration or a bending vibration for the question) For the NMR spect for product 8, draw the structure of the product next to the spectrum and label the prote they match the labels shown on the NMR spectrum Fil in the Chemical shi, donand mulipácity in the table STRUCTURE Doublet Prote a H (ppm) L Explain the multiplicity and relative integration for the peak labda Explain the multiplicity and relativa integration for the peak abeed Hr.

d. For the spectrum for product, identify which functional groups are suggested by the signals indicated by each of the include whether the signal is d to a stretching vibration or a bending vibration for the question) For the NMR spect for product 8, draw the structure of the product next to the spectrum and label the prote they match the labels shown on the NMR spectrum Fil in the Chemical shi, donand mulipácity in the table STRUCTURE Doublet Prote a H (ppm) L Explain the multiplicity and relative integration for the peak labda Explain the multiplicity and relativa integration for the peak abeed Hr.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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