(d) What is the molarity of MCIO3 in Solution A? 2. Use the identity of MCIO3 and the decomposition equation above to answer the following questions: (a) Calculate the enthalpy of formation (AH) of MCI. (b) If you performed the decomposition reaction of Solution A in a coffee-cup calorimeter, what would be the final temperature of the solution if the initial temperature was 25.0 °C? Assume cal = 0 and that the specific heat and densities of the solution are the same as that of water. AHf of MCIO3, next page.

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Chapter1: Chemical Foundations
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Only Answer questions 1 - d and 2 a-b

Answers to questions 1 a-c 

a. Number of moles of O2 = 0.0613 mol

b. Number of moles of MClO3= 0.040836 mol

c. The Molar mass is 122.44 g/mol , The mystery substance is KClO3

You found a container with a white substance labeled MClO₃ but you do not know which Group 1 metal M represents. You decide to use your chemistry wizardry to identify this mystery substance. You dissolve 5.00 g in enough water to produce 250. mL of the solution (Solution A). You decompose the chlorate according to the following reaction:

\[ 2MClO₃ \, (aq) \rightarrow 2MCl \, (aq) + 3O₂ \, (g) \quad \Delta H_{rxn} = -140.2 \, \text{kJ} \]

1. You collect the O₂ produced and it has a volume of 1.53 L at a temperature of 25.0 °C and 0.980 atm.

   (a) How many moles of O₂ were produced?

   (b) How many moles of MClO₃ reacted?

   (c) What is the molar mass and the identity of the mystery substance?
Transcribed Image Text:You found a container with a white substance labeled MClO₃ but you do not know which Group 1 metal M represents. You decide to use your chemistry wizardry to identify this mystery substance. You dissolve 5.00 g in enough water to produce 250. mL of the solution (Solution A). You decompose the chlorate according to the following reaction: \[ 2MClO₃ \, (aq) \rightarrow 2MCl \, (aq) + 3O₂ \, (g) \quad \Delta H_{rxn} = -140.2 \, \text{kJ} \] 1. You collect the O₂ produced and it has a volume of 1.53 L at a temperature of 25.0 °C and 0.980 atm. (a) How many moles of O₂ were produced? (b) How many moles of MClO₃ reacted? (c) What is the molar mass and the identity of the mystery substance?
(d) What is the **molarity** of \( \text{MClO}_3 \) in Solution A?

2. Use the identity of \( \text{MClO}_3 \) and the decomposition equation above to answer the following questions:
   
   (a) Calculate the **enthalpy of formation** (\( \Delta H_f \)) of MCl.

   (b) If you performed the decomposition reaction of Solution A in a coffee-cup calorimeter, what would be the **final temperature** of the solution if the initial temperature was 25.0 °C? Assume \( q_{\text{cal}} = 0 \) and that the specific heat and densities of the solution are the same as that of water. \( \Delta H_f \) of \( \text{MClO}_3 \), next page.
Transcribed Image Text:(d) What is the **molarity** of \( \text{MClO}_3 \) in Solution A? 2. Use the identity of \( \text{MClO}_3 \) and the decomposition equation above to answer the following questions: (a) Calculate the **enthalpy of formation** (\( \Delta H_f \)) of MCl. (b) If you performed the decomposition reaction of Solution A in a coffee-cup calorimeter, what would be the **final temperature** of the solution if the initial temperature was 25.0 °C? Assume \( q_{\text{cal}} = 0 \) and that the specific heat and densities of the solution are the same as that of water. \( \Delta H_f \) of \( \text{MClO}_3 \), next page.
Expert Solution
Step 1

#1: #(d):

The identity of the chlorate is KClO3 with a molar mass of 122.44 g/mol 

Moles of KClO3 in the solution = 0.040836 mol 

Volume of solution A = 250. mL * 1 L1000 mL = 0.250 L

 

 

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