D-Pinitol is an interesting hexahydroxy cyclohexane, whose structure is shown below. HO OH HO/4 HO ОН On the templates provided, draw the two chair conformations that are in equilibrium for D-pinitol. Circle the most stable conformation. 6 3 2 1 OH

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Question 27
### D-Pinitol: An Insight into Hexahydroxy Cyclohexane

#### Introduction to D-Pinitol

D-Pinitol is an intriguing compound within the family of hexahydroxy cyclohexanes. Below is its molecular structure representation.

#### Molecular Structure
The diagram shows a cyclohexane ring numbered from 1 to 6 displaying hydroxyl groups (HO) attached to the carbon atoms. The hydroxyl groups are specifically located at:
- Carbon 1 (HO)
- Carbon 2 (HO)
- Carbon 3 (HO)
- Carbon 4 (HO)
- Carbon 5 (HO)

#### Task: Chair Conformations in Equilibrium

To understand D-pinitol better, let's delve into its conformational analysis. Cyclohexane and its derivatives often adopt chair conformations due to their stability. These conformations undergo equilibrium, shifting between two distinct forms.

#### Exercise: Drawing Chair Conformations 

Using the provided templates, students are asked to draw the two chair conformations of D-pinitol. Additionally, they need to identify and **circle the most stable conformation**.

The transition between the two forms is represented as an arrow connecting the chair structures. Pay close attention to the placement of the hydroxyl groups in each conformation, as their axial or equatorial positions directly impact the overall stability.

By understanding these structural nuances, students can gain deeper insights into cyclohexane chemistry and the factors influencing molecular stability.
Transcribed Image Text:### D-Pinitol: An Insight into Hexahydroxy Cyclohexane #### Introduction to D-Pinitol D-Pinitol is an intriguing compound within the family of hexahydroxy cyclohexanes. Below is its molecular structure representation. #### Molecular Structure The diagram shows a cyclohexane ring numbered from 1 to 6 displaying hydroxyl groups (HO) attached to the carbon atoms. The hydroxyl groups are specifically located at: - Carbon 1 (HO) - Carbon 2 (HO) - Carbon 3 (HO) - Carbon 4 (HO) - Carbon 5 (HO) #### Task: Chair Conformations in Equilibrium To understand D-pinitol better, let's delve into its conformational analysis. Cyclohexane and its derivatives often adopt chair conformations due to their stability. These conformations undergo equilibrium, shifting between two distinct forms. #### Exercise: Drawing Chair Conformations Using the provided templates, students are asked to draw the two chair conformations of D-pinitol. Additionally, they need to identify and **circle the most stable conformation**. The transition between the two forms is represented as an arrow connecting the chair structures. Pay close attention to the placement of the hydroxyl groups in each conformation, as their axial or equatorial positions directly impact the overall stability. By understanding these structural nuances, students can gain deeper insights into cyclohexane chemistry and the factors influencing molecular stability.
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